N-BUTYLCYCLOPENTADIENYLZIRCONIUM TRICHLORIDE

Base Information

• Chemical Name: N-BUTYLCYCLOPENTADIENYLZIRCONIUM TRICHLORIDE
• CAS No.: 329735-75-3
• Molecular Formula: C9H13 Cl3 Zr
• Molecular Weight: 318.785
• Mol file: 329735-75-3.mol

Synonyms:(n-Butylcyclopentadienyl)zirconiumtrichloride

Chemical Property of N-BUTYLCYCLOPENTADIENYLZIRCONIUM TRICHLORIDE

Chemical Property:

• PSA: 0.00000
• LogP: 4.65040
• Sensitive.: moisture sensitive, store cold

Purity/Quality:

98%Min ^*data from raw suppliers

n-Butylcyclopentadienylzirconium trichloride ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-BUTYLCYCLOPENTADIENYLZIRCONIUM TRICHLORIDE

There total 1 articles about N-BUTYLCYCLOPENTADIENYLZIRCONIUM TRICHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

bis(n-butylcyclopentadienyl)zirconium dichloride (73364-10-0) + zirconium(IV) chloride (10026-11-6) → (2-butylcyclopenta-2,4-dienyl)zirconium(IV) chloride (329735-75-3)

Guidance literature:

In toluene; at 20 ℃; for 20h; Heating / reflux;

Reference yield: 73.0%

(2-butylcyclopenta-2,4-dienyl)zirconium(IV) chloride (329735-75-3) + Li[(C9H6)-1-(3-phenylpropyl)] → Zr{η5-C5H4-[(CH2)3CH3]}{η5-C9H6-1-[(CH2)3Ph]}Cl2

Guidance literature:

In diethyl ether; at 0 - 20 ℃;

Reference yield: 27.0%

(2-butylcyclopenta-2,4-dienyl)zirconium(IV) chloride (329735-75-3) + lithium 4-(3,5-di-tert-butyl-4-methoxyphenyl)-2-methyl-1H-inden-1-ide → (4-(3,5-di-tert-butyl-4-methoxyphenyl)-2-methyl-1H-inden-1-yl)(n-butylcyclpentadienyl)zirconium dichloride

Guidance literature:

In diethyl ether; at 20 ℃; for 17h; Inert atmosphere; Glovebox;

upstream raw materials:

bis(n-butylcyclopentadienyl)zirconium dichloride

zirconium(IV) chloride

Refernces