SAMARIUM ACETATE HYDRATE

Base Information

• Chemical Name: SAMARIUM ACETATE HYDRATE
• CAS No.: 100587-91-5
• Molecular Formula: 3C₂H₃O₂*4H₂O*Sm
• Molecular Weight: 399.555
• Mol file: 100587-91-5.mol

Synonyms:Aceticacid, samarium(3+) salt, hydrate (9CI); Samarium acetate hydrate; Samariumtriacetate hydrate

Chemical Property of SAMARIUM ACETATE HYDRATE

Chemical Property:

• PSA: 88.13000
• Density: 1,94 g/cm3
• LogP: -0.02290

Purity/Quality:

98%,99%, ^*data from raw suppliers

Samarium(III) acetate hydrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of SAMARIUM ACETATE HYDRATE

There total 1 articles about SAMARIUM ACETATE HYDRATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

samarium(III) oxide → samarium(III) acetate tetrahydrate (14842-17-2,15280-52-1,17829-85-5,17829-86-6,17829-87-7,21308-08-7,70457-50-0,100587-91-5)

Guidance literature:

With acetic acid; In acetic acid; aq. acetic acid; 25% acetic acid, 70 to 80°C, evapn.; filtered, washed with ether, dried at 30 to 35°C to constant weight;

Reference yield: 47.0%

samarium(III) acetate tetrahydrate (14842-17-2,15280-52-1,17829-85-5,17829-86-6,17829-87-7,21308-08-7,70457-50-0,100587-91-5) + 1,2-dibenzyloxy-4,5-dicyanobenzene (206995-45-1) → samarium(III) 2,3,9,10,116,117,23,24,2',3',9',10',16',17',23',24'-hexadecabenzyloxy(diphthalocyanine)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In hexane; mixt. of 4,5-dibenzyloxyphthalonitrile, metal salt, 1,8-diazabicyclo(5.4.0)undec-7-ene was refluxed in n-hexanol under Ar for 8 h; cooled; filtered off; washed (aq. MeOH); residue pptd. from DMF with H2O; chromd. on silica gel (benzene-MeOH, 10:1 as eluent); chromd. on Al2O3;

DOI:10.1007/s11172-006-0082-9

Reference yield: 43.21%

1,10-Phenanthroline (66-71-7) + samarium(III) acetate tetrahydrate (14842-17-2,15280-52-1,17829-85-5,17829-86-6,17829-87-7,21308-08-7,70457-50-0,100587-91-5) + 3-chlorobenzoate (535-80-8) → C66H40Cl6N4O12Sm2*2H2O

Guidance literature:

With ammonia; water; In ethanol; at 70 ℃; for 15h; pH=6.8;

Downstream raw materials:

cobalt(II) oxide