5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

Base Information

• Chemical Name: 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
• CAS No.: 16456-81-8
• Molecular Formula: C44H28ClFeN4
• Molecular Weight: 704.033
• Hs Code.: 29349990
• Mol file: 16456-81-8.mol

Synonyms:Chloro(tetraphenylporphyrinato)iron(III);Cl(meso-Tetraph-P)iron;Fe(III)Tppcl;Tetraphenylporphyrinatoiron(III) chloride;Iron, chloro(5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24)-, (SP-5-12)-;

Chemical Property of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

Chemical Property:

• Melting Point: 300 °C
• PSA: 34.58000
• LogP: 7.12480
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: Insoluble in water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

Iron(III) meso-tetraphenylporphine chloride ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Iron(III) meso-tetraphenylporphine chloride is used catalyzing reagent for silylation reactions.

Technology Process of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

There total 36 articles about 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.4%

iron(II) chloride tetrahydrate + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8)

Guidance literature:

In N,N-dimethyl-formamide; for 0.5h; Reflux;

DOI:10.1021/op060056z

Reference yield: 97.4%

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8)

Guidance literature:

5,15,10,20-tetraphenylporphyrin; With iron(II) chloride tetrahydrate; In N,N-dimethyl-formamide; for 0.5h;

With hydrogenchloride; In water; at 50 - 60 ℃;

DOI:10.3390/molecules16042960

Reference yield: 85.0%

iron(III) chloride + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → 5,10,15,20-tetraphenyl-21H,23H-porphine iron(lll) chloride (16456-81-8)

Guidance literature:

In N,N-dimethyl-formamide; at 200 ℃; for 1h;

DOI:10.1002/anie.202110190

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

5,15,10,20-tetraphenylporphyrin

μ-oxo-bis[α,β,γ,δ-tetraphenylporphinatoiron]

chloride

Downstream raw materials:

iron(II) nitrosyl meso-(tetraphenyl) porphyrinate

Fe[C₄H₂NCC₆H₅]4(C₂H₅OH)2

μ-oxo-bis[α,β,γ,δ-tetraphenylporphinatoiron]

(C₆H₅)4C₂₀H₈N₄Fe(CC(O)CH₂C(CH₃)2CH₂C(O))2

Refernces

• 1、 Xu, Weijie,Fang, Yuanyuan,Ou, Zhongping,Chen, Mingyuan,Kadish, Karl M.. "Synthesis, electrochemical and spectroelectrochemical characterization of iron(III) tetraarylporphyrins containing four β, β ′-butano and β, β ′-benzo fused rings". . p. 521 - 534. Retrieved 2018.
• 2、 Liston, David J.,Murray, Keith S.,West, Bruce O.. "The Formation of Heterobinuclear μ-Oxo Cr-O-Fe Porphyrin Complexes by the Reaction of Oxochromium(IV) and Iron(II) Porphyrins". . p. 1109 - 1111. Retrieved 1982.
• 3、 Doeff, Marca M.,Sweigart. "Hydrogen bonding in metalloporphyrin reactions. Reaction of (tetraphenylporphinato)iron(III) chloride and N-methylimidazole". . p. 3699 - 3705. Retrieved 1982.
• 4、 Liu, Guiyu,Fan, Ying-Jie,Zhang, Jun-Long. "Construction of secondary coordination sphere boosts electrochemical CO 2 reduction of iron porphyrins". . p. 465 - 472. Retrieved 2020.
• 5、 Kondo, Mio,Kosugi, Kento,Masaoka, Shigeyuki. "Quick and Easy Method to Dramatically Improve the Electrochemical CO2 Reduction Activity of an Iron Porphyrin Complex". . p. 22070 - 22074. Retrieved 2021.
• 6、 Pegis, Michael L.,Martin, Daniel J.,Wise, Catherine F.,Brezny, Anna C.,Johnson, Samantha I.,Johnson, Lewis E.,Kumar, Neeraj,Raugei, Simone,Mayer, James M.. "Mechanism of Catalytic O2 Reduction by Iron Tetraphenylporphyrin". . p. 8315 - 8326. Retrieved 2020.