5,10,15-Tri(pentafluorophenyl)corrole

Base Information

• Chemical Name: 5,10,15-Tri(pentafluorophenyl)corrole
• CAS No.: 238402-21-6
• Molecular Formula: C₃₇H₁₁F₁₅N₄
• Molecular Weight: 796.497
• Mol file: 238402-21-6.mol

Synonyms:5,10,15-TRI(PENTAFLUOROPHENYL)CORROLE

Chemical Property of 5,10,15-Tri(pentafluorophenyl)corrole

Chemical Property:

• PSA: 52.87000
• LogP: 6.58380

Purity/Quality:

99% ^*data from raw suppliers

5,10,15-TRI(PENTAFLUOROPHENYL)CORROLE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5,10,15-Tri(pentafluorophenyl)corrole

There total 15 articles about 5,10,15-Tri(pentafluorophenyl)corrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

5,5'-((perfluorophenyl)methylene)bis(2-((perfluorophenyl)(1H-pyrrol-2-yl)methyl)-1H-pyrrole) (925900-28-3) → 5,10,15-tris(pentafluorophenyl)corrole (238402-21-6)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; at 15 ℃; for 0.5h;

DOI:10.1002/ejoc.201500276

Reference yield: 44.0%

5,5'-((perfluorophenyl)methylene)bis(2-((perfluorophenyl)(1H-pyrrol-2-yl)methyl)-1H-pyrrole) (925900-28-3) → 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole (238402-21-6)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; at 20 ℃; for 1h; Reagent/catalyst;

DOI:10.1002/ejoc.201403217

Reference yield: 30.0%

pyrrole (109-97-7,30604-81-0) + perfluorobenzaldehyde (653-37-2) → 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole (238402-21-6)

Guidance literature:

pyrrole; perfluorobenzaldehyde; With Amberlyst 15; at 20 ℃;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; at 20 ℃; for 0.25h; Further stages.;

DOI:10.1002/jhet.5570450323

upstream raw materials:

pyrrole

perfluorobenzaldehyde

1,9-bis(pentafluorophenylhydroxymethyl)-5-(pentafluorophenyl)dipyrromethane

(((perfluorophenyl)methylene)bis(1H-pyrrole-5,2-diyl))bis((perfluorophenyl)methanone)

Downstream raw materials:

5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)

Refernces

• 1、 Simkhovich, Liliya,Goldberg, Israel,Gross, Zeev. "Easy preparation of cobalt corrole and hexaphyrin and isolation of new oligopyrroles in the solvent-free condensation of pyrrole with pentafluorobenzaldehyde". . p. 1241 - 1244. Retrieved 2003.
• 2、 Collman, James P.,Decréau, Richard A.. "Microwave-assisted synthesis of corroles". . p. 1207 - 1210. Retrieved 2003.
• 3、 Barata, Joana F.B.,Zamarrón, Alicia,Neves, M. Grac? P.M.S.,Faustino, M. Amparo F.,Tomé, Augusto C.,Cavaleiro, José A.S.,R?der, Beate,Juarranz, ángeles,Sanz-Rodríguez, Francisco. "Photodynamic effects induced by meso-tris(pentafluorophenyl)corrole and its cyclodextrin conjugates on cytoskeletal components of HeLa cells". . p. 135 - 144. Retrieved 2015.
• 4、 Fisher, Julia M.,Kensy, Victoria K.,Geier, G. Richard. "Two-Step, One-Flask Synthesis of an N-Confused Porphyrin Bearing Pentafluorophenyl Substituents". . p. 4429 - 4434. Retrieved 2017.