1H,1H-PERFLUORO-1-NONANOL

Base Information

• Chemical Name: 1H,1H-PERFLUORO-1-NONANOL
• CAS No.: 423-56-3
• Molecular Formula: C9H3F17O
• Molecular Weight: 450.095
• Hs Code.: 29055900
• Mol file: 423-56-3.mol

Synonyms:2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-Heptadecafluoro-1-nonanol;1,1-Dihydroperfluoronon-1-yl alcohol;Perfluorooctylmethanol;1H,1H-Perfluoro-1-nonanol;1,1-Dihydroperfluoro-1-nonanol;(Heptadecafluorooctyl)methanol;

Chemical Property of 1H,1H-PERFLUORO-1-NONANOL

Chemical Property:

• Appearance/Colour: white transparent crystals
• Vapor Pressure: 0.335mmHg at 25°C
• Melting Point: 66-69 ºC
• Refractive Index: 1.285
• Boiling Point: 176.4 ºC at 760 mmHg
• PKA: 12.88±0.10(Predicted)
• Flash Point: 60.5 ºC
• PSA: 20.23000
• Density: 1.681 g/cm³
• LogP: 4.98810
• Storage Temp.: -20°C Freezer, Under inert atmosphere
• Solubility.: DMSO (Slightly), Methanol (Slightly)
• Water Solubility.: Insoluble in water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

Perfluorooctylmethanol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 1H,1H-Perfluoro-1-nonanol is used to produce other chemicals. For example, it is used to produce Trifluoro-methanesulfonic acid 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro-nonyl ester. This reaction needs reagent Pyridine and solvent CHCl3

Technology Process of 1H,1H-PERFLUORO-1-NONANOL

There total 4 articles about 1H,1H-PERFLUORO-1-NONANOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyloxymethyloxirane → 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononanol (423-56-3) + 3-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyloxy)propene-1

Guidance literature:

Multi-step reaction with 2 steps

1: thiourea / methanol

2: 210 - 215 °C

With thiourea; In methanol;

DOI:10.1134/S1070363214110139

Reference yield:

perfluorononanoic acid (375-95-1) → 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononanol (423-56-3)

Guidance literature:

With lithium aluminium tetrahydride; diethyl ether;

Reference yield:

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyloxymethylthiirane → 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononanol (423-56-3) + 3-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyloxy)propene-1

Guidance literature:

at 210 - 215 ℃;

DOI:10.1134/S1070363214110139

upstream raw materials:

perfluorononanoic acid

Downstream raw materials:

acrylic acid-(1H,1H-heptadecafluoro-nonyl ester)

C₃₂H₃₄F₁₇NO₂

C₂₁H₁₉F₁₇N₂O

Refernces