thiotrithiazyl chloride

Base Information

• Chemical Name: thiotrithiazyl chloride
• CAS No.: 857244-78-1
• Molecular Formula: Cl*N₃S₄
• Molecular Weight: 205.737
• Mol file: 857244-78-1.mol

Synonyms:thiotrithiazyl chloride

Chemical Property of thiotrithiazyl chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of thiotrithiazyl chloride

There total 9 articles about thiotrithiazyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

bis(triphenylphosphine)iminium trisulfur trinitride → sulfur (10544-50-0) + thiotrithiazyl chloride (857244-78-1) + tetrasulphur tetranitride (127770-66-5)

Guidance literature:

With chlorine; In dichloromethane; byproducts: NH4Cl, PPNCl; Cl2 was passed into stirred soln. of PPNS3N3 in CH2Cl2 at -78°C for 16 h; filtered off, solvent was removed in vac., extd. with CH2Cl2, crystd.;

Reference yield: 39.0%

Cs(1+)*S3N3(1-)=CsS3N3 → thiotrithiazyl chloride (857244-78-1) + tetrasulphur tetranitride (127770-66-5) + bis(sulfinylamino)sulfane (77133-46-1,13840-74-9) + cesium chloride (15690-63-8,64704-31-0,7647-17-8)

Guidance literature:

With thionyl chloride; In acetonitrile; SOCl2 was added to stirred soln. of CsS3N3 in CH3CN at 23°C for 7 h; filtered off, solvent was removed in vac., extd. with CH3CN, crystd.;

Reference yield:

thiodithiacyl chloride → disulfur dichloride (10025-67-9) + thiotrithiazyl chloride (857244-78-1)

Guidance literature:

In neat (no solvent); decompn. on smooth heating;;

upstream raw materials:

acetyl chloride

tetrasulfur tetranitride

disulfur dichloride

trithiazyl monochloride

Downstream raw materials:

hydrogenchloride

(Pt(S₂N₂)(Ph₂PCH₂CH₂PPh₂))

sulfur

trithionate

Refernces

• 1、 Chivers, Tristram,Rao, M. N. Shudheendra. "Reactions of the trisulfur trinitride anion, S3N3-, with halogens and other electrophilic substrates". . p. 1957 - 1962. Retrieved 2007/10/02.