5-AMINO-2-NITROBENZOIC ACID

Base Information

• Chemical Name: 5-AMINO-2-NITROBENZOIC ACID
• CAS No.: 132080-60-5
• Molecular Formula: C₂₀H₂₄O₃
• Molecular Weight: 312.409
• Mol file: 132080-60-5.mol

Synonyms:3CARBOXY4NITROANILINE;2NITRO5AMINOBENZOICACID;TIMTECBBSBB008583

Chemical Property of 5-AMINO-2-NITROBENZOIC ACID

Chemical Property:

• Vapor Pressure: 4.5E-10mmHg at 25°C
• Melting Point: 236-238℃(lit.)
• Boiling Point: 184.4°Cat760mmHg
• Flash Point: 70°C
• PSA: 51.21000
• Density: 1.015g/cm³
• LogP: 4.70180
• Water Solubility.: Insoluble

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 36/37/38-22
• Safety Statements: 37/39-26

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-AMINO-2-NITROBENZOIC ACID

There total 3 articles about 5-AMINO-2-NITROBENZOIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

10-undecenoic acid (112-38-9) → 10-(1,4-Naphthochinon-2-yl)decanal (132080-60-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 27 percent / (NH₄)2S₂O₈ / AgNO₃ / acetonitrile; H₂O / 0.17 h / Heating

2: 1) Disiamylboran, 2) PCC / 1) Et₂O, 0 deg C, 3h, 2) CH₂Cl₂, 2h, reflux

With ammonium peroxydisulfate; Disiamylboran; pyridinium chlorochromate; silver nitrate; In water; acetonitrile;

Reference yield:

[1,4]naphthoquinone (130-15-4) → 10-(1,4-Naphthochinon-2-yl)decanal (132080-60-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 27 percent / (NH₄)2S₂O₈ / AgNO₃ / acetonitrile; H₂O / 0.17 h / Heating

2: 1) Disiamylboran, 2) PCC / 1) Et₂O, 0 deg C, 3h, 2) CH₂Cl₂, 2h, reflux

With ammonium peroxydisulfate; Disiamylboran; pyridinium chlorochromate; silver nitrate; In water; acetonitrile;

Reference yield:

2-(Dec-9-enyl)-1,4-naphthochinon (132080-59-2) → 10-(1,4-Naphthochinon-2-yl)decanal (132080-60-5)

Guidance literature:

With Disiamylboran; pyridinium chlorochromate; Yield given. Multistep reaction; 1) Et₂O, 0 deg C, 3h, 2) CH₂Cl₂, 2h, reflux;

upstream raw materials:

2-(Dec-9-enyl)-1,4-naphthochinon

10-undecenoic acid

[1,4]naphthoquinone

Refernces