2,3-BIS(HYDROXYMETHYL)NAPHTHALENE

Base Information

• Chemical Name: 2,3-BIS(HYDROXYMETHYL)NAPHTHALENE
• CAS No.: 31554-15-1
• Molecular Formula: C12H12O2
• Molecular Weight: 188.226
• Hs Code.: 2906299090
• Mol file: 31554-15-1.mol

Synonyms:2,3-Bishydroxymethylnaphthalene;

Chemical Property of 2,3-BIS(HYDROXYMETHYL)NAPHTHALENE

Chemical Property:

• Melting Point: 157 °C
• Boiling Point: 400.9 °C at 760 mmHg
• Flash Point: 201.5 °C
• PSA: 40.46000
• Density: 1.244g/cm³
• LogP: 1.82440
• Storage Temp.: Refrigerator

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,3-Naphthalenedimethanol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Intermediate in the preparation of Naphthalene-2,3-dicarboxaldehyde (N356000).

Technology Process of 2,3-BIS(HYDROXYMETHYL)NAPHTHALENE

There total 17 articles about 2,3-BIS(HYDROXYMETHYL)NAPHTHALENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2,3-Naphthalenedicarboxylic anhydride (716-39-2) → 2,3-bis(hydroxymethyl)naphthalene (31554-15-1)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 - 20 ℃; for 6h; Inert atmosphere;

DOI:10.1021/jo502248p

Reference yield: 100.0%

naphthalene-2,3-dicarboxylic acid (2169-87-1) → 2,3-bis(hydroxymethyl)naphthalene (31554-15-1)

Guidance literature:

With borane-THF; In tetrahydrofuran; at 0 - 20 ℃; for 24h; Inert atmosphere;

DOI:10.1021/ja302537j

Reference yield: 96.0%

dimethyl 2,3-naphthalenedicarboxylate (13728-34-2) → 2,3-bis(hydroxymethyl)naphthalene (31554-15-1)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 ℃; for 0.5h;

DOI:10.1002/jccs.200200013

upstream raw materials:

2,3-Naphthalenedicarboxylic anhydride

2,3-bis-acetoxymethyl-naphthalene

naphthalene-2,3-dicarboxylic acid

2,3-naphthalenedicarboxaldehyde

Downstream raw materials:

2,3-di(bromomethyl)naphthalene

triisopropyl(3-phenylanthracen-2-yloxy)silane

2,3-naphthalenedicarboxaldehyde

anthracene-2,3 dicarboxaldehyde

Refernces

• 1、 Wang, Cong,Hill, Malik,Theard, Brandon,MacK, James. "A solvent-free mechanochemical synthesis of polyaromatic hydrocarbon derivatives". . p. 27888 - 27891. Retrieved 2019.
• 2、 Einholz, Ralf,Fang, Treliant,Berger, Robert,Grüninger, Peter,Früh, Andreas,Chassé, Thomas,Fink, Reinhold F.,Bettinger, Holger F.. "Heptacene: Characterization in Solution, in the Solid State, and in Films". supporting information. p. 4435 - 4442. Retrieved 2017/04/03.