butane-2,3-dione mono-oxime

Base Information

• Chemical Name: butane-2,3-dione mono-oxime
• CAS No.: 135636-66-7
• Molecular Formula: C₄H₇NO₂
• Molecular Weight: 101.105
• Mol file: 135636-66-7.mol

Synonyms:butane-2,3-dione mono-oxime

Chemical Property of butane-2,3-dione mono-oxime

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of butane-2,3-dione mono-oxime

There total 14 articles about butane-2,3-dione mono-oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

menthol (15356-70-4) + cyclohexanone oxime acrylate (86198-29-0) → (-)-menthyl acrylate (4835-96-5) + (1S,2R,5S)‐2‐isopropyl‐5‐methylcyclohexyl acrylate (108945-28-4) + butane-2,3-dione mono-oxime (135636-66-7)

Guidance literature:

With porcine pancreatic lipase; In tetrahydrofuran; at 35 ℃; Yields of byproduct given;

DOI:10.1039/c39890001533

Reference yield: 57.52%

2,3-butanedione mono-(O-acetyl oxime) (17292-61-4) + cyclohexanol (108-93-0) → cyclohexyl acetate (622-45-7) + butane-2,3-dione mono-oxime (135636-66-7)

Guidance literature:

With porcine pancreatic lipase; In tetrahydrofuran; at 35 ℃; for 48h;

DOI:10.1039/c39890001533

Reference yield:

butane-2,3-dione dioxime (95-45-4) → dimethylglyoxal (431-03-8) + butane-2,3-dione mono-oxime (135636-66-7)

Guidance literature:

With sulfuric acid;

upstream raw materials:

butane-2,3-dione dioxime

menthol

cyclohexanone oxime acrylate

2,3-butanedione mono-(O-acetyl oxime)

Downstream raw materials:

2,3-butanedione mono-(O-acetyl oxime)

2,4,5-trimethyl-3-formylpyrrole

2,4,5-trimethyl-3-ethoxycarbonylpyrrole

1,1-dinitroethane

Refernces

• 1、 Mitchell,Cameron. "". . p. 1968. Retrieved 1938.
• 2、 Makarycheva-Mikhailova, Anastassiya V.,Haukka, Matti,Bokach, Nadezhda A.,Garnovskii, Dmitrii A.,Galanski, Markus,Keppler, Bernhard K.,Pombeiro, Armando J. L.,Kukushkin, Vadim Yu.. "Platinum(IV)-mediated coupling of dione monoximes and nitriles: A novel reactivity pattern of the classic oxime-based chelating ligands". . p. 1085 - 1091. Retrieved 2007/10/03.