1,2:5,6-di-O-isopropylidene-D-talo-hexitol

Base Information

• Chemical Name: 1,2:5,6-di-O-isopropylidene-D-talo-hexitol
• CAS No.: 53735-99-2
• Molecular Formula: C₁₂H₂₂O₆
• Molecular Weight: 262.303
• Mol file: 53735-99-2.mol

Synonyms:1,2:5,6-di-O-isopropylidene-D-talo-hexitol

Chemical Property of 1,2:5,6-di-O-isopropylidene-D-talo-hexitol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2:5,6-di-O-isopropylidene-D-talo-hexitol

There total 2 articles about 1,2:5,6-di-O-isopropylidene-D-talo-hexitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ (2R,3R,4R,5R)-Mannit-1,2,5,6-diacetonid (1707-77-3,22323-78-0,53735-98-1,53735-99-2,60134-06-7,64870-23-1,82188-74-7,102418-34-8,120442-07-1)

Guidance literature:

D-Mannit, Dimethoxypropan/ p-TsOH;

Reference yield:

O4-benzoyl-O1,O2;O5,O6-diisopropylidene-D-arabino-[3]hexulose (101864-30-6) → 1,2:5,6-di-O-isopropylidene-D-talo-hexitol (53735-99-2) + 1,2:5,6-di-O-isopropylidene-D-mannitol (1707-77-3)

Guidance literature:

With lithium aluminium tetrahydride; diethyl ether;

DOI:10.1021/ja01578a051

Reference yield:

1,2:5,6-di-O-isopropylidene-D-talo-hexitol (53735-99-2) → 2,3-isopropylidene-glyceraldehyde (15186-48-8)

Guidance literature:

With sodium periodate; sodium hydrogencarbonate; sodium sulfate; In dichloromethane; water; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1021/ol503261h

upstream raw materials:

O⁴-benzoyl-O¹,O²;O⁵,O⁶-diisopropylidene-D-arabino-[3]hexulose

Downstream raw materials:

D-talitol

2,3-isopropylidene-glyceraldehyde