Technology Process of Mercury, chloro(cyclohexyl)
There total 3 articles about Mercury, chloro(cyclohexyl) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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With
acetic acid; sodium chloride;
In
tetrahydrofuran; water;
to Grignard reagent in THF is slowly added mercuric chloride in THF, mixt. is warmed to reflux for 1 h, colled to room temp., poured into aq. acetic acid contg. NaCl; solid is collected and dried, dissolving in CHCl3, filtn., concg. soln., recrystn. from EtOH;
DOI:10.1021/om00093a020
- Guidance literature:
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In
[(2)H6]acetone;
byproducts: ClSi(OCH2CH2)3N; excess HgCl2, 50°C; not isolated, reaction followed by (1)H-NMR spectroscopy;
Kinetics;
DOI:10.1016/0022-328X(85)80362-4
- Guidance literature:
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1) Bis-(trimethylsilyl)-quecksilber, Methoxycyclohexan, 2) ethanol. HCl;