1-Bromo-6-phenylhexane

Base Information

• Chemical Name: 1-Bromo-6-phenylhexane
• CAS No.: 27976-27-8
• Molecular Formula: C12H17Br
• Molecular Weight: 241.171
• Hs Code.: 2903999090
• Mol file: 27976-27-8.mol

Synonyms:Hexane,1-bromo-6-phenyl- (6CI,8CI);(6-Bromohexyl)benzene;(6-Bromohexyl)benzol;1-Bromo-6-phenylhexane;6-Bromo-1-phenylhexane;6-Phenylhexyl bromide;

Chemical Property of 1-Bromo-6-phenylhexane

Chemical Property:

• Vapor Pressure: 0.00218mmHg at 25°C
• Refractive Index: 1.5295
• Boiling Point: 299 °C at 760 mmHg
• Flash Point: 158.1 °C
• PSA: 0.00000
• Density: 1.197 g/cm³
• LogP: 4.18440
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

1-Bromo-6-phenylhexane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Bromo-6-phenylhexane

There total 29 articles about 1-Bromo-6-phenylhexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1 ,6-dibromohexane (629-03-8) + bromobenzene (108-86-1,52753-63-6) → (6-bromohexyl)benzene (27976-27-8)

Guidance literature:

bromobenzene; With n-butyllithium; In tetrahydrofuran; at -85 ℃; for 3h; Inert atmosphere;

1 ,6-dibromohexane; In tetrahydrofuran; at -20 ℃; for 4h; Temperature; Inert atmosphere;

Reference yield: 77.0%

6-phenyl-1-hexanol (2430-16-2) → (6-bromohexyl)benzene (27976-27-8)

Guidance literature:

With carbon tetrabromide; triphenylphosphine; In dichloromethane; for 1h;

DOI:10.1021/jm00158a021

Reference yield: 70.0%

1 ,6-dibromohexane (629-03-8) + phenyllithium (591-51-5) → (6-bromohexyl)benzene (27976-27-8)

Guidance literature:

In tetrahydrofuran; diethyl ether; hexane; at -14 - 20 ℃; for 7h; Inert atmosphere;

DOI:10.1002/anie.201101821

upstream raw materials:

6-phenyl-1-hexanol

5-hexen-2-ylbenzene

1 ,6-dibromohexane

phenyllithium

Downstream raw materials:

1-(6-phenyl-hexyl)-piperazine

6-phenyl-hexane-1-sulfonic acid

Thiosulfuric acid S-[2-(6-phenyl-hexylamino)-ethyl] ester

5-Methyl-4-(6-phenyl-hexylsulfanylmethyl)-1H-imidazole

Refernces

• 1、 Liu, Shiwen,Zeng, Xiaojun,Hammond, Gerald B.,Xu, Bo. "Mild Base Promoted Nucleophilic Substitution of Unactivated sp3-Carbon Electrophiles with Alkenylboronic Acids". supporting information. p. 3667 - 3671. Retrieved 2018/09/12.
• 2、 Sheng, Xingfeng,Wang, Yong,Qin, Yusheng,Wang, Xianhong,Wang, Fosong. "Aluminum porphyrin complexes via delicate ligand design: Emerging efficient catalysts for high molecular weight poly(propylene carbonate)". . p. 54043 - 54050. Retrieved 2015/02/02.