Vinyl phenyl acetate

Base Information

• Chemical Name: Vinyl phenyl acetate
• CAS No.: 18120-64-4
• Molecular Formula: C10H10O2
• Molecular Weight: 162.188
• Hs Code.: 2916399090
• Mol file: 18120-64-4.mol

Synonyms:Phenyl but-3-enoate;

Chemical Property of Vinyl phenyl acetate

Chemical Property:

• Boiling Point: 242.3 °C at 760 mmHg
• Flash Point: 93.3 °C
• PSA: 26.30000
• Density: 1.045 g/cm³
• LogP: 1.91580

Purity/Quality:

98%Min ^*data from raw suppliers

VINYL PHENYL ACETATE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Vinyl phenyl acetate

There total 6 articles about Vinyl phenyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

phenylacetic acid (103-82-2) + 2,4,6-trivinylcyclotriboroxane*pyridine complex → vinyl ester of phenylacetic acid (18120-64-4)

Guidance literature:

With N,N'-diethylurea; copper(II) bis(trifluoromethanesulfonate); triethylamine; In tetrahydrofuran; at 50 ℃; for 16h;

DOI:10.1002/adsc.201800914

Reference yield: 86.0%

phenylacetic acid (103-82-2) + vinyl acetate (108-05-4,9003-20-7) → vinyl ester of phenylacetic acid (18120-64-4)

Guidance literature:

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In toluene; at 65 ℃; for 16h; Reagent/catalyst; Inert atmosphere;

DOI:10.1021/acs.joc.0c02135

Reference yield:

→ vinyl ester of phenylacetic acid (18120-64-4)

Guidance literature:

With toluene; at 180 - 185 ℃; Einleiten von Acetylen;

upstream raw materials:

acetaldehyde

phenylacetyl chloride

(formylmethyl)mercury chloride

phenylacetic acid

Downstream raw materials:

6'-O-phenylacetyl-arbutin

1-O-(phenylacetyl)-7-O-butyrylcastanospermine

1-O-(phenylacetyl)-6-O-butyrylcastanospermine

1-O-butyryl-7-O-(phenylacetyl)castanospermine

Refernces

• 1、 Young, Claire M.,Taylor, James E.,Smith, Andrew D.. "Evaluating aryl esters as bench-stable C(1)-ammonium enolate precursors in catalytic, enantioselective Michael addition-lactonisations". supporting information. p. 4747 - 4752. Retrieved 2019/05/24.
• 2、 Krejzova, Jana,Simon, Petr,Vavrikova, Eva,Slamova, Kristyna,Pelantova, Helena,Riva, Sergio,Spiwok, Vojtech,Kren, Vladimir. "Enzymatic synthesis of new C-6-acylated derivatives of NAG-thiazoline and evaluation of their inhibitor activities towards fungal β-N- acetylhexosaminidase". . p. 128 - 134. Retrieved 2013/03/13.