1-(4-methoxyphenyl)-2,3,3-trichloro-1-oxopropene

Base Information

• Chemical Name: 1-(4-methoxyphenyl)-2,3,3-trichloro-1-oxopropene
• CAS No.: 133473-98-0
• Molecular Formula: C₁₀H₇Cl₃O₂
• Molecular Weight: 265.523
• Mol file: 133473-98-0.mol

Synonyms:1-(4-methoxyphenyl)-2,3,3-trichloro-1-oxopropene

Chemical Property of 1-(4-methoxyphenyl)-2,3,3-trichloro-1-oxopropene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(4-methoxyphenyl)-2,3,3-trichloro-1-oxopropene

There total 2 articles about 1-(4-methoxyphenyl)-2,3,3-trichloro-1-oxopropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

2,3,3-trichloroacryloyl chloride (815-58-7) + methoxybenzene (100-66-3) → 2,3,3-Trichloro-1-(2-hydroxy-phenyl)-propenone (75399-39-2) + 1-(4-methoxyphenyl)-2,3,3-trichloro-1-oxopropene (133473-98-0)

Guidance literature:

With aluminium trichloride; In dichloromethane; Yields of byproduct given; Ambient temperature;

DOI:10.1021/jo00010a027

Reference yield:

2,3,3-trichloroacryloyl chloride (815-58-7) + methoxybenzene (100-66-3) → 1-(4-methoxyphenyl)-2,3,3-trichloro-1-oxopropene (133473-98-0)

Guidance literature:

With carbon disulfide; aluminium trichloride;

Reference yield: 99.0%

1-(4-methoxyphenyl)-2,3,3-trichloro-1-oxopropene (133473-98-0) → 1-(4-methoxyphenyl)-2,3,3-trichloro-1-hydroxy-2-propene (114703-29-6)

Guidance literature:

With sodium tetrahydroborate; In ethanol; Ambient temperature; regioselective reduction; other trichlorovinyl ketones;

DOI:10.1021/jo00010a027

upstream raw materials:

2,3,3-trichloroacryloyl chloride

methoxybenzene

Downstream raw materials:

1-(4-methoxyphenyl)-2,3,3-trichloro-1-hydroxy-2-propene

Refernces