p-methylbenzyl phenylmethanethiosulphinate

Base Information

• Chemical Name: p-methylbenzyl phenylmethanethiosulphinate
• CAS No.: 73975-38-9
• Molecular Formula: C₁₅H₁₆OS₂
• Molecular Weight: 276.423
• Mol file: 73975-38-9.mol

Synonyms:p-methylbenzyl phenylmethanethiosulphinate

Chemical Property of p-methylbenzyl phenylmethanethiosulphinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-methylbenzyl phenylmethanethiosulphinate

There total 3 articles about p-methylbenzyl phenylmethanethiosulphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

phenylmethanesulfinyl chloride (41719-05-5) + 4-methylbenzylthiol (4498-99-1) → p-methylbenzyl phenylmethanethiosulphinate (73975-38-9)

Guidance literature:

With triethylamine; In diethyl ether; at -20 ℃; for 0.333333h;

DOI:10.1039/P29800000432

Reference yield:

dibenzyl disulphide (150-60-7) → p-methylbenzyl phenylmethanethiosulphinate (73975-38-9)

Guidance literature:

Multi-step reaction with 2 steps

1: chlorine / acetic anhydride / -10 °C

2: 64 percent / triethylamine / diethyl ether / 0.33 h / -20 °C

With chlorine; triethylamine; In diethyl ether; acetic anhydride;

DOI:10.1039/P29800000432

Reference yield:

petivericin (16302-98-0) → p-methylbenzyl phenylmethanethiosulphinate (73975-38-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 65 percent / CF₃CO₂H

2: chlorine / acetic anhydride / -10 °C

3: 64 percent / triethylamine / diethyl ether / 0.33 h / -20 °C

With chlorine; triethylamine; trifluoroacetic acid; In diethyl ether; acetic anhydride;

DOI:10.1039/P29800000432

upstream raw materials:

phenylmethanesulfinyl chloride

4-methylbenzylthiol

dibenzyl disulphide

petivericin

Downstream raw materials:

petivericin

α-acetylthiobenzyl benzyl sulphoxide

(α-acetylthio)-p-methylbenzyl benzyl sulphoxide

Refernces