SODIUM TRIMETHYLSILANOLATE

Base Information

• Chemical Name: SODIUM TRIMETHYLSILANOLATE
• CAS No.: 18027-10-6
• Molecular Formula: C3H9NaOSi
• Molecular Weight: 112.179
• Hs Code.: 29319090
• Mol file: 18027-10-6.mol

Synonyms:Silanol,trimethyl-, sodium salt (8CI,9CI);Sodium, (trimethylsiloxy)- (7CI);Sodiumtrimethylsilanoate;Sodium trimethylsilanolate;Sodium trimethylsiloxide;Trimethylsilanol sodium salt;Trimethylsilyloxysodium;

Chemical Property of SODIUM TRIMETHYLSILANOLATE

Chemical Property:

• Melting Point: 230 °C (dec.)(lit.)
• Boiling Point: 75 °C at 760 mmHg
• Flash Point: -2 °F
• PSA: 23.06000
• Density: 1.283 g/mL at 25 °C
• LogP: 1.25180

Purity/Quality:

99% ^*data from raw suppliers

Sodium Trimethyl Silanolate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,C,F
• Hazard Codes: T,C,F
• Statements: 34-40-23/24/25-20/21/22-19-11-37
• Safety Statements: 26-36/37/39-45-28-27-16

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of SODIUM TRIMETHYLSILANOLATE

There total 8 articles about SODIUM TRIMETHYLSILANOLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

Trimethylsilanol (1066-40-6) → sodium trimethylsilanolate (18027-10-6)

Guidance literature:

With NaOH; In sodium hydroxide; aq. NaOH; (CH3)3SiOH and 12N aq. NaOH under cooling;;

DOI:10.1021/ja01215a047

Reference yield: 80.0%

Hexamethyldisiloxane (107-46-0) → sodium trimethylsilanolate (18027-10-6)

Guidance literature:

With NaNH₂; In ammonia; NH3 (liquid);

DOI:10.1021/ja01118a042

Reference yield:

→ sodium trimethylsilanolate (18027-10-6)

Guidance literature:

Herstellung;

DOI:10.1021/jo50012a001 DOI:10.1021/ja01118a042

upstream raw materials:

Hexamethyldisiloxane

Trimethylmethoxysilane

ethyl trimethylsilyl ether

Trimethylsilanol

Downstream raw materials:

1-chloro-1,1,3,3,3-pentamethyldisiloxane

(2-bromocyclohexyloxy)trimethylsilane

1-tert-butyl-1-chloro-3,3,3-trimethyl-1-phenyl-disiloxane

1-chloro-3,3,3-trimethyl-1-phenyl-1-(2,4,6-tri-iso-propylphenyl)disiloxane

Refernces

• 1、 Lovric, Marija,Cepanec, Ivica,Litvic, Mladen,Bartolincic, Anamarija,Vinkovic, Vladimir. "Scope and limitations of sodium and potassium trimethylsilanolate as reagents for conversion of esters to carboxylic acids". . p. 109 - 115. Retrieved 2008/02/04.