Cyclobutylphenylsulfide

Base Information

• Chemical Name: Cyclobutylphenylsulfide
• CAS No.: 67132-84-7
• Molecular Formula: C10H12S
• Molecular Weight: 294.45368
• Hs Code.: 2930909090
• DSSTox Substance ID: DTXSID70460091
• Nikkaji Number: J2.210.741K
• Wikidata: Q82284005
• Mol file: 67132-84-7.mol

Synonyms:Cyclobutylphenylsulfide;67132-84-7;Cyclobutylsulfanylbenzene;cyclobutylphenyl sulfide;SCHEMBL4696488;DTXSID70460091;AKOS006331420;FT-0657150

Chemical Property of Cyclobutylphenylsulfide

Chemical Property:

• PSA: 25.30000
• LogP: 3.33120
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 164.06597156
• Heavy Atom Count: 11
• Complexity: 112

Purity/Quality:

99% ^*data from raw suppliers

CYCLOBUTYLPHENYLSULFIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC(C1)SC2=CC=CC=C2

Technology Process of Cyclobutylphenylsulfide

There total 5 articles about Cyclobutylphenylsulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

cyclobutanone (1191-95-3) + thiophenol (108-98-5) → cyclobutyl phenyl sulfide (67132-84-7)

Guidance literature:

With triethylsilane; trifluoroacetic acid; In dichloromethane; at 20 ℃; for 6h;

DOI:10.1080/00304940509354887

Reference yield: 40.0%

cyclobutanone (1191-95-3) + thiophenol (108-98-5) → cyclobutyl phenyl sulfide (67132-84-7) + 1,1-bis(phenylthio)cyclobutane (125790-47-8)

Guidance literature:

With boron trifluoride diethyl etherate;

DOI:10.1080/00304940509354887

Reference yield: 26.0%

cyclobutyl 4-methylbenzenesulfonate (10437-85-1) + thiophenol (108-98-5) → (cyclopropylmethyl)(phenyl)sulfane (53911-82-3) + cyclobutyl phenyl sulfide (67132-84-7) + homoallyl phenyl sulfide (4285-49-8)

Guidance literature:

With potassium carbonate; sodium iodide; In N,N-dimethyl acetamide; at 130 ℃;

DOI:10.1080/00304940509354887

upstream raw materials:

bicyclo[1.1.0]butane

thiophenol

cyclobutanone

cyclobutyl 4-methylbenzenesulfonate

Downstream raw materials:

cyclobutyl phenyl sulfoxide

1-(1-Phenylsulfanyl-cyclobutyl)-cyclohexanol

(cyclobutylsulfonyl)benzene

Refernces

• 1、 Fyfe, Matthew C. T.,Rasamison, Chrystelle M.. "Reductive thiolation approach to pure cyclobutyl phenyl sulfide". . p. 194 - 197. Retrieved 2007/10/03.