S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl) benzenethio-sulfonate

Base Information

• Chemical Name: S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl) benzenethio-sulfonate
• CAS No.: 1346231-33-1
• Molecular Formula: C₁₅H₂₃Cl₃O₅S₂Si
• Molecular Weight: 481.921
• Mol file: 1346231-33-1.mol

Synonyms:S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl) benzenethio-sulfonate

Chemical Property of S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl) benzenethio-sulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl) benzenethio-sulfonate

There total 7 articles about S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl) benzenethio-sulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

S-(2-(2-(2-allyloxy-ethoxy)-ethoxy)-ethyl) benzenethiosulfonate (1352078-77-3) → S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl) benzenethio-sulfonate (1346231-33-1)

Guidance literature:

With trichlorosilane; dihydrogen hexachloroplatinate(IV) hexahydrate; at 20 ℃; for 21h;

Reference yield:

ethylene glycol monoallyl ether (111-45-5,27274-31-3) → S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl) benzenethio-sulfonate (1346231-33-1)

Guidance literature:

Multi-step reaction with 7 steps

1.1: sodium hydride / tetrahydrofuran / 1 h / 20 °C / Reflux

1.2: 0.25 h / 0 °C

2.1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / 0 °C

3.1: sodium hydride / tetrahydrofuran / 1 h / 20 °C / Reflux

3.2: 0.25 h / 0 °C

4.1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / 0 °C

5.1: pyridine; sodium bromide; phosphorus tribromide / diethyl ether / 24.5 h / 0 - 20 °C / Reflux

6.1: acetonitrile / Reflux

7.1: trichlorosilane / dihydrogen hexachloroplatinate(IV) hexahydrate / 21 h / 20 °C

With pyridine; lithium aluminium tetrahydride; trichlorosilane; phosphorus tribromide; sodium hydride; sodium bromide; dihydrogen hexachloroplatinate(IV) hexahydrate; In tetrahydrofuran; diethyl ether; acetonitrile;

Reference yield:

2-(2-allyloxyethoxy)ethanol (15075-50-0,27274-31-3) → S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl) benzenethio-sulfonate (1346231-33-1)

Guidance literature:

Multi-step reaction with 5 steps

1.1: sodium hydride / tetrahydrofuran / 1 h / 20 °C / Reflux

1.2: 0.25 h / 0 °C

2.1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / 0 °C

3.1: pyridine; sodium bromide; phosphorus tribromide / diethyl ether / 24.5 h / 0 - 20 °C / Reflux

4.1: acetonitrile / Reflux

5.1: trichlorosilane / dihydrogen hexachloroplatinate(IV) hexahydrate / 21 h / 20 °C

With pyridine; lithium aluminium tetrahydride; trichlorosilane; phosphorus tribromide; sodium hydride; sodium bromide; dihydrogen hexachloroplatinate(IV) hexahydrate; In tetrahydrofuran; diethyl ether; acetonitrile;

upstream raw materials:

ethylene glycol monoallyl ether

2-(2-allyloxyethoxy)ethanol

2-(2-(2-(allyloxy)ethoxy)ethoxy)ethanol

Methyl (2-allyloxy-ethoxy)-acetate

Refernces