Chlorobis(ethylene)Iridium(I)Dimer

Base Information

• Chemical Name: Chlorobis(ethylene)Iridium(I)Dimer
• CAS No.: 39722-81-1
• Molecular Formula: C8H16 Cl2 Ir2
• Molecular Weight: 567.561
• Mol file: 39722-81-1.mol

Synonyms:Bis((m-chloro)bis(h2-ethylene)iridium);Bis(chlorobis(h2-ethylene)iridium);Bis(ethylene)chloroiridium dimer; Chlorobis(ethylene)iridium dimer; Di-m-Chlorotetrakis(ethene)diiridium;Dichlorotetrakis(ethene)diiridium

Chemical Property of Chlorobis(ethylene)Iridium(I)Dimer

Chemical Property:

• PSA: 0.00000
• LogP: 3.60380
• Storage Temp.: 0-10°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Chlorobis(ethylene)iridium(I) Dimer >95.0%(T) ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Chlorobis(ethylene)Iridium(I)Dimer

There total 1 articles about Chlorobis(ethylene)Iridium(I)Dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chlorobis(cyclooctene)-iridium(I) dimer + ethene (74-85-1) → di-μ-chlorotetrakis(ethene)diiridium(I) (39722-81-1)

Guidance literature:

In pentane; at -20 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejic.201800169

Reference yield: 99.0%

di-μ-chlorotetrakis(ethene)diiridium(I) (39722-81-1) + thallium hydrotris(3,4,5-tribromopyrazolil)borate (850339-57-0,461386-24-3) → [(hydridotris(3,4,5-tribromo)pyrazolylborate)Ir(C2H4)2]

Guidance literature:

In tetrahydrofuran; byproducts: TlCl; (N2); standard Schlenk technique; Tl compd. was added to soln. of Ir complex in THF at 0°C; suspn. was stirred at 10°C for 3 h; solvent pumped off; residue extd. (CH2Cl2); filtered; solvent removed;

DOI:10.1021/om034242u

Reference yield: 97.0%

di-μ-chlorotetrakis(ethene)diiridium(I) (39722-81-1) + 8,8'-(4,5-difluorobenzene)diquinoline → C26H18ClF2IrN2

Guidance literature:

In tetrahydrofuran; for 10h; Inert atmosphere;

DOI:10.1021/acs.organomet.1c00250

upstream raw materials:

ethene

Downstream raw materials:

IrCl(C₂H₄)[((CH₃)2CH)2PCH₂CO₂CH₃]2

trans-[IrCl(ethene)(As(i)Pr₃)2]

[(CH₂CH₂)2Ir(N₂CHCHC(CH₂NC₅H₁₀))]2

Ir(C₂H₄)(N(i-Pr₂PS)2

Refernces