Diacetato(1,10-phenanthroline)palladium(II)

Base Information

• Chemical Name: Diacetato(1,10-phenanthroline)palladium(II)
• CAS No.: 35679-81-3
• Molecular Formula: C16H14 N2 O4 Pd
• Molecular Weight: 404.718
• Mol file: 35679-81-3.mol

Synonyms:Palladium,bis(acetato-O)(1,10-phenanthroline-N1,N10)-, (SP-4-2)-; 1,10-Phenanthroline,palladium complex; (1,10-Phenanthroline)palladium(II) acetate;Bis(acetato)(1,10-phenanthroline)palladium

Chemical Property of Diacetato(1,10-phenanthroline)palladium(II)

Chemical Property:

• PSA: 76.04000
• LogP: 1.11960

Purity/Quality:

99% ^*data from raw suppliers

Diacetato(1,10-phenanthroline)palladium(II), 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diacetato(1,10-phenanthroline)palladium(II)

There total 3 articles about Diacetato(1,10-phenanthroline)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

[Pd(OAc){C6H3(CO2Me)2-3,4}(phen)] + acetic acid (64-19-7,77671-22-8) → (1,10-phenanthroline)-palladium(II) acetate (35679-81-3) + phthalic acid dimethyl ester (131-11-3,64441-70-9)

Guidance literature:

at 100 ℃; for 0.5h;

DOI:10.1021/acscatal.8b01095

Reference yield: 96.0%

[Pd(OAc){C6H3(CO2Me)2-2,3}(phen)] + acetic acid (64-19-7,77671-22-8) → (1,10-phenanthroline)-palladium(II) acetate (35679-81-3) + phthalic acid dimethyl ester (131-11-3,64441-70-9)

Guidance literature:

at 100 ℃; for 0.5h;

DOI:10.1021/acscatal.8b01095

Reference yield: 75.0%

Pd[(μ-O2CMe)2Ag(HO2CMe)2]2 (1308661-15-5) + 1,10-phenanthroline hydrate (5144-89-8) → (1,10-phenanthroline)-palladium(II) acetate (35679-81-3) + silver(I) acetate (563-63-3)

Guidance literature:

In benzene; benzene soln. of ligand added with stirring to benzene soln. of Pd compd. (1:1 molar ratio), mixt. stirred at room temp. for 30 min; ppt. filtered off, concd., pptd. (heptane), dried, elem. anal.;

DOI:10.1016/j.ica.2011.02.003

upstream raw materials:

Pd[(μ-O2CMe)2Ag(HO2CMe)2]2

1,10-phenanthroline hydrate

acetic acid

Downstream raw materials:

Pd(1,10-phenanthroline){N(C₆H₅)C(O)N(C₆H₅)C(O)N(C₆H₅)}

Refernces

• 1、 Hirano, Masafumi,Sano, Kosuke,Kanazawa, Yuki,Komine, Nobuyuki,Maeno, Zen,Mitsudome, Takato,Takaya, Hikaru. "Mechanistic Insights on Pd/Cu-Catalyzed Dehydrogenative Coupling of Dimethyl Phthalate". . p. 5827 - 5841. Retrieved 2018/05/29.