3-Decylthiophene

Base Information

• Chemical Name: 3-Decylthiophene
• CAS No.: 65016-55-9
• Molecular Formula: C14H24S
• Molecular Weight: 224.411
• Hs Code.: 29349990
• Mol file: 65016-55-9.mol

Synonyms:3-Decylthiophene;3-n-Decylthiophene;

Chemical Property of 3-Decylthiophene

Chemical Property:

• Vapor Pressure: 0.00213mmHg at 25°C
• Melting Point: -10.15°C (estimate)
• Refractive Index: n20/D 1.489(lit.)
• Boiling Point: 299.4 °C at 760 mmHg
• Flash Point: 99.1 °C
• PSA: 29.10000
• Density: 0.92 g/cm³
• LogP: 3.84910
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

3-Decylthiophene ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 3-Decylthiophene

There total 6 articles about 3-Decylthiophene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

3-Bromothiophene (872-31-1) + 1-bromo dodecane (112-29-8) → 3-decylthiophene (65016-55-9,110851-65-5)

Guidance literature:

1-bromo dodecane; With iodine; magnesium; In diethyl ether; for 2h; Inert atmosphere; Reflux;

3-Bromothiophene; With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); In diethyl ether; for 16h; Inert atmosphere; Reflux;

DOI:10.1039/c5tc00531k

Reference yield: 78.0%

3-Bromothiophene (872-31-1) + Iododecane (2050-77-3) → 3-decylthiophene (65016-55-9,110851-65-5)

Guidance literature:

With N,N,N,N,-tetramethylethylenediamine; di-tert-butyl[dichloro({di-tert-butyl[4-(dimethylamino)phenyl]phosphaniumyl})palladio][4-(dimethylamino)phenyl]phosphanium; zinc; In water; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.tetlet.2010.11.160

Reference yield: 78.0%

3-Bromothiophene (872-31-1) + n-decyl magnesium bromide (17049-50-2) → 3-decylthiophene (65016-55-9,110851-65-5)

Guidance literature:

With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); In tetrahydrofuran; for 15h; Reflux;

DOI:10.1039/c4tc02347a

upstream raw materials:

3-Bromothiophene

1-bromo dodecane

n-decyl magnesium bromide

Iododecane

Downstream raw materials:

2-bromo-3-decylthiophene

5,5'''-dibromo-3,3'''-didecyl-2,2':5',2'':5'',2'''-quaterthiophene

5,5''-dibromo-3,3''-didecyl-2,2':5',2''-terthiophene

3,3'''-didecyl-2,2':5',2'':5'',2'''-quaterthiophene

Refernces

• 1、 Gao, Hongfei,Cheng, Huifang,Yang, Zonghan,Prehm, Marko,Cheng, Xiaohong,Tschierske, Carsten. "Synthesis and self-assembly of 5,5′-bis(phenylethynyl)-2,2′-bithiophene-based bolapolyphiles in triangular and square LC honeycombs". supporting information. p. 1301 - 1308. Retrieved 2015/02/19.
• 2、 Quinton, Cassandre,Chi, San-Hui,Dumas-Verdes, Ccile,Audebert, Pierre,Clavier, Gilles,Perry, Joseph W.,Alain-Rizzo, Valrie. "Novel s-tetrazine-based dyes with enhanced two-photon absorption cross-section". supporting information. p. 8351 - 8357. Retrieved 2015/08/18.