9,10-Bis(2-naphthyl)anthracene-2-ylboronic acid

Base Information

• Chemical Name: 9,10-Bis(2-naphthyl)anthracene-2-ylboronic acid
• CAS No.: 867044-28-8
• Molecular Formula: C34H23 B O2
• Molecular Weight: 474.366
• Hs Code.: 2931900090
• Mol file: 867044-28-8.mol

Synonyms:Boronicacid, (9,10-di-2-naphthalenyl-2-anthracenyl)- (9CI);

Chemical Property of 9,10-Bis(2-naphthyl)anthracene-2-ylboronic acid

Chemical Property:

• Boiling Point: 685.5 °C at 760 mmHg
• PKA: 8.43±0.30(Predicted)
• Flash Point: 368.4 °C
• PSA: 40.46000
• Density: 1.32 g/cm³
• LogP: 7.31320
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

Boronicacid,(9,10-di-2-naphthalenyl-2-anthracenyl)- ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9,10-Bis(2-naphthyl)anthracene-2-ylboronic acid

There total 7 articles about 9,10-Bis(2-naphthyl)anthracene-2-ylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-bromo-9,10-di(2-naphthyl)anthracene (474688-76-1) + Trimethyl borate (121-43-7,63156-11-6) → (9,10-di (naphthalene-2-yl) anthracene-2-yl)boronic acid (867044-28-8)

Guidance literature:

2-bromo-9,10-di(2-naphthyl)anthracene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 2h; Inert atmosphere;

Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 17h; Inert atmosphere;

Reference yield: 84.0%

2-bromo-9,10-di(2-naphthyl)anthracene (474688-76-1) + Triisopropyl borate (5419-55-6) → (9,10-di (naphthalene-2-yl) anthracene-2-yl)boronic acid (867044-28-8)

Guidance literature:

2-bromo-9,10-di(2-naphthyl)anthracene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h;

Triisopropyl borate; In tetrahydrofuran; at 20 ℃;

With hydrogenchloride; In tetrahydrofuran; water; at 0 ℃;

Reference yield: 61.2%

2-bromo-9,10-di(2-naphthyl)anthracene (474688-76-1) + Triisopropyl borate (5419-55-6) + water (7732-18-5) → (9,10-di (naphthalene-2-yl) anthracene-2-yl)boronic acid (867044-28-8)

Guidance literature:

2-bromo-9,10-di(2-naphthyl)anthracene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1.5h;

Triisopropyl borate; In tetrahydrofuran; at 20 ℃; for 24h;

water; With hydrogenchloride; In tetrahydrofuran;

upstream raw materials:

2-bromo-9,10-di(2-naphthyl)anthracene

Trimethyl borate

Triisopropyl borate

water

Downstream raw materials:

C₄₇H₃₀N₂

2-(2-nitrophenyl)-9,10-di(2-naphthyl)anthracene

6,11-di(2-naphthyl)-13H-13-aza-indeno[1,2-b]anthracene

6,11-di(2-naphthyl)-13-methyl-13-azaindeno[1,2-b]anthracene

Refernces

• 1、 -. "Semiconducting Material Comprising Aza-Substituted Phosphine Oxide Matrix and Metal Salt". . . Retrieved 2016/05/11.
• 2、 -. "MULTICYCLIC COMPOUND HAVING NITROGEN AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME". Paragraph 0214-0217. . Retrieved 2016/10/09.