2-Methoxyiminofurylacetic acid amonium salt

Base Information

• Chemical Name: 2-Methoxyiminofurylacetic acid amonium salt
• CAS No.: 97148-89-5
• Molecular Formula: C₁₄H₂₆OOsS
• Molecular Weight: 432.626
• Mol file: 97148-89-5.mol

Synonyms:Benzene,1-methyl-4-(1-methylethyl)-, osmium complex;

Chemical Property of 2-Methoxyiminofurylacetic acid amonium salt

Chemical Property:

• Vapor Pressure: 0.00138mmHg at 25°C
• Melting Point: 182
• Boiling Point: 284.7 °C at 760 mmHg
• Flash Point: 126 °C
• PSA: 75.27000
• LogP: 1.03860

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): R11:
• Hazard Codes: F:Flammable
• Statements: R11:
• Safety Statements: S2:; S22:; S43:

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Methoxyiminofurylacetic acid amonium salt

There total 1 articles about 2-Methoxyiminofurylacetic acid amonium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trimethylaluminium dimer + (CH3C6H4CH(CH3)2)OsCl2((CH3)2SO) (97148-86-2) → (CH3C6H4CH(CH3)2)Os(CH3)Cl((CH3)2SO) + ((CH3C6H4CH(CH3)2)Os((CH3)2SO)(CH3)2) (97148-89-5)

Guidance literature:

In toluene; to suspn. ((p-MeC6H4CHMe2)Os(Me2SO)Cl2) in toluene contg. Me2SO soln. Al2Me6 in toluene (molar ratio 1:1.59) was added slowly, after stirring for 10 min acetone followed by water was added dropwise and stirred for 20 min; Et2O added, solid filtered off, soln. vac.-evapd. to dryness, oil dissolved in Et2O-MeCOMe(3:1) and chromd. on alumina under Ar, elution with Et2O, crystals washed with light petroleum, dried in Ar-stream (product mixt. contg. 11% of Me2-complex, NMR);

DOI:10.1039/DT9850000573

upstream raw materials:

(CH₃C₆H₄CH(CH₃)2)OsCl₂((CH₃)2SO)

Refernces