BENZOIC ACID, 2-IODYL, 1-METHYLETHYL ESTER

Base Information

• Chemical Name: BENZOIC ACID, 2-IODYL, 1-METHYLETHYL ESTER
• CAS No.: 674776-90-0
• Molecular Formula: C10H11IO4
• Molecular Weight: 322.099
• Mol file: 674776-90-0.mol

Synonyms:Isopropyl 2-iodylbenzoate;

Chemical Property of BENZOIC ACID, 2-IODYL, 1-METHYLETHYL ESTER

Chemical Property:

• PSA: 60.44000
• LogP: 2.61880

Purity/Quality:

99% ^*data from raw suppliers

BenzoicAcid,2-Iodyl,1-MethylethylEster 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BENZOIC ACID, 2-IODYL, 1-METHYLETHYL ESTER

There total 2 articles about BENZOIC ACID, 2-IODYL, 1-METHYLETHYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

2-iodobenzoic acid isopropyl ester (79780-05-5) → 2-iodylbenzoic acid 1-methylethyl ester (674776-90-0)

Guidance literature:

With sodium hypochlorite; In dichloromethane;

DOI:10.1055/s-2004-834873

Reference yield:

2-Iodobenzoyl chloride (609-67-6) → 2-iodylbenzoic acid 1-methylethyl ester (674776-90-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 93 percent / 0.5 h / Heating

2: 89 percent / sodium hypochlorite / CH₂Cl₂; H₂O

With sodium hypochlorite; In dichloromethane; water;

DOI:10.1021/jo051010r

Reference yield:

[Fe(N4Py2Ar1)(CH3CN)](BF4)2 + 2-iodylbenzoic acid 1-methylethyl ester (674776-90-0) → [Fe(O)(N4Py2Ar1)(CH3CN)](BF4)2*acetonitrile

Guidance literature:

In acetonitrile; at -20 ℃;

DOI:10.1021/jacs.6b03346

upstream raw materials:

2-iodobenzoic acid isopropyl ester

2-Iodobenzoyl chloride

Refernces

• 1、 Koposov, Alexey Y.,Zhdankin, Viktor V.. "Selective oxidation of sulfides to sulfoxides using IBX-esters". . p. 22 - 24. Retrieved 2007/10/03.
• 2、 Zhdankin, Viktor V.,Litvinov, Dmitry N.,Koposov, Alexey Y.,Luu, Thanh,Ferguson, Michael J.,McDonald, Robert,Tykwinski, Rik R.. "Preparation and structure of 2-iodoxybenzoate esters: Soluble and stable periodinane oxidizing reagents". . p. 106 - 107. Retrieved 2007/10/03.