1,1-dimethyl-1,2-dihydrocyclobutabenzene

Base Information

• Chemical Name: 1,1-dimethyl-1,2-dihydrocyclobutabenzene
• CAS No.: 56846-74-3
• Molecular Formula: C₁₀H₁₂
• Molecular Weight: 132.205
• Mol file: 56846-74-3.mol

Synonyms:1,1-dimethyl-1,2-dihydrocyclobutabenzene

Chemical Property of 1,1-dimethyl-1,2-dihydrocyclobutabenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1-dimethyl-1,2-dihydrocyclobutabenzene

There total 32 articles about 1,1-dimethyl-1,2-dihydrocyclobutabenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

C26H33IN3OPd(1+)*I(1-) → (2-methyl-1-propenyl)-benzene (768-49-0) + 1,1-dimethyl-1,2-dihydrocyclobutabenzene (56846-74-3) + 1-iodo-2-methyl-2-phenylpropane (19479-63-1) + (2-iodo-2-methylpropyl)benzene + C16H21IN3OPd(1+)*I(1-)

Guidance literature:

In chloroform; at 50 ℃; for 7.5h; Solvent; Kinetics;

DOI:10.1021/acs.organomet.0c00615

Reference yield: 90.0%

C25H31BrN3OPd(1+)*Br(1-) → (2-methyl-1-propenyl)-benzene (768-49-0) + 1,1-dimethyl-1,2-dihydrocyclobutabenzene (56846-74-3) + 2-methyl-2-phenyl-propyl bromide (3756-32-9) + C15H19BrN3OPd(1+)*Br(1-)

Guidance literature:

In chloroform; at 50 ℃; for 7.5h; Kinetics;

DOI:10.1021/acs.organomet.0c00615

Reference yield: 87.0%

C25H31IN3OPd(1+)*I(1-) → (2-methyl-1-propenyl)-benzene (768-49-0) + 1,1-dimethyl-1,2-dihydrocyclobutabenzene (56846-74-3) + 1-iodo-2-methyl-2-phenylpropane (19479-63-1) + (2-iodo-2-methylpropyl)benzene + C15H19IN3OPd(1+)*I(1-)

Guidance literature:

In chloroform; at 50 ℃; for 7.5h; Reagent/catalyst; Solvent; Kinetics;

DOI:10.1021/acs.organomet.0c00615

upstream raw materials:

3-(2-phenyl-2-propyl)diazirine

[(bpy)Pd^IV(CH₂CMe₂-o-C₆H₄)(F)(OTf)]

[(bpy)Pd^IV(CH₂CMe₂-o-C₆H₄)(F)(NHTs)]

sodium phenoxide

Refernces

• 1、 Wang, Hao-Ran,Wang, Xi–Chao,Xu, Xiufang,Zhao, Dongbing. "Ring Expansion to 8-Membered Silacycles through Formal Cross-Dimerization of 5-Membered Palladacycles with Silacyclobutanes". supporting information. p. 3039 - 3042. Retrieved 2021/07/22.
• 2、 Watson, Michael B.,Rath, Nigam P.,Mirica, Liviu M.. "Oxidative C-C bond formation reactivity of organometallic Ni(II), Ni(III), and Ni(IV) complexes". supporting information. p. 35 - 38. Retrieved 2017/05/16.