6-[3-(10-phenyl-9-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan

Base Information

• Chemical Name: 6-[3-(10-phenyl-9-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan
• CAS No.: 1382763-45-2
• Molecular Formula: C₄₂H₂₆O
• Molecular Weight: 546.668
• Mol file: 1382763-45-2.mol

Synonyms:6-[3-(10-phenyl-9-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan

Chemical Property of 6-[3-(10-phenyl-9-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-[3-(10-phenyl-9-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan

There total 7 articles about 6-[3-(10-phenyl-9-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

9-(3-bromophenyl)-10-phenylanthracene (1023674-80-7) + (benzo[b]naphtho[1,2-d]furan-6-yl)boronic acid (1382763-54-3) → 6-[3-(10-phenyl-9-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan (1382763-45-2)

Guidance literature:

With potassium carbonate; tris-(o-tolyl)phosphine; palladium diacetate; In ethanol; water; at 80 ℃; for 4h; Inert atmosphere;

Reference yield:

benzo[b]naphtho[1,2-d]furan (205-39-0) → 6-[3-(10-phenyl-9-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan (1382763-45-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sec.-butyllithium; 2,3-dimethyl-2,3-diaminobutane / cyclohexane; hexane; tetrahydrofuran / 2 h / -80 °C / Inert atmosphere

1.2: 48 h / 20 °C / Inert atmosphere

2.1: potassium carbonate; tris-(o-tolyl)phosphine / palladium diacetate / ethanol; water / 4 h / 80 °C / Inert atmosphere

With 2,3-dimethyl-2,3-diaminobutane; sec.-butyllithium; potassium carbonate; tris-(o-tolyl)phosphine; palladium diacetate; In tetrahydrofuran; ethanol; hexane; cyclohexane; water; 2.1: Suzuki-Miyaura Coupling;

Reference yield:

o-fluorophenylboronic acid (1993-03-9) → 6-[3-(10-phenyl-9-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan (1382763-45-2)

Guidance literature:

Multi-step reaction with 4 steps

1.1: potassium carbonate; tris-(o-tolyl)phosphine / palladium diacetate / toluene; ethanol; water / 6.5 h / 80 - 100 °C / Inert atmosphere

2.1: potassium carbonate / 1-methyl-pyrrolidin-2-one / 6 h / 150 °C / Inert atmosphere

3.1: sec.-butyllithium; 2,3-dimethyl-2,3-diaminobutane / cyclohexane; hexane; tetrahydrofuran / 2 h / -80 °C / Inert atmosphere

3.2: 48 h / 20 °C / Inert atmosphere

4.1: potassium carbonate; tris-(o-tolyl)phosphine / palladium diacetate / ethanol; water / 4 h / 80 °C / Inert atmosphere

With 2,3-dimethyl-2,3-diaminobutane; sec.-butyllithium; potassium carbonate; tris-(o-tolyl)phosphine; palladium diacetate; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; ethanol; hexane; cyclohexane; water; toluene; 1.1: Suzuki-Miyaura coupling / 2.1: Williamson ether Synthesis / 4.1: Suzuki-Miyaura Coupling;

upstream raw materials:

o-fluorophenylboronic acid

1-bromo-2-methoxynaphthalene

1-bromo-2-naphthol

9-(3-bromophenyl)-10-phenylanthracene

Refernces

• 1、 -. "Benzo[b]Naphtho[1,2-d]Furan Compound as Light-Emitting Element Material". . . Retrieved 2012/07/13.