Gallium(III) trifluoromethanesulfonate

Base Information

• Chemical Name: Gallium(III) trifluoromethanesulfonate
• CAS No.: 74974-60-0
• Molecular Formula: C3F9GaO9S3
• Molecular Weight: 516.93
• Hs Code.: 29319090
• European Community (EC) Number: 688-219-3
• DSSTox Substance ID: DTXSID80370051
• Nikkaji Number: J1.383.321D
• Mol file: 74974-60-0.mol

Synonyms:74974-60-0;GALLIUM(III) TRIFLUOROMETHANESULFONATE;gallium tris(trifluoromethanesulfonate);Gallium(III) trifluoromethanesulphonate;gallium;trifluoromethanesulfonate;Methanesulfonic acid, trifluoro-, gallium salt;MFCD02093898;gallium trifluoromethanesulfonate;Galium(III) triflate;gallium (III) triflate;C3F9GaO9S3;AMY9079;DTXSID80370051;BVLXNPRUOXPBII-UHFFFAOYSA-K;galliumtris(trifluoromethanesulfonate);AKOS015909389;GS-6321;SC10883;SY064750;CS-0044524;FT-0658451;gallium(3+) ion tritrifluoromethanesulfonate;H10893;A838285;GALLIUM TRIFLATE;GALLIUM(III) TRIFLUOROMETHANESULPHONATE;TRIFLUOROMETHANESULFONIC ACID GALLIUM(III) SALT

Chemical Property of Gallium(III) trifluoromethanesulfonate

Chemical Property:

• Vapor Pressure: 1.14mmHg at 25°C
• Boiling Point: 162°C at 760 mmHg
• PSA: 196.74000
• Density: 1.7g/cm³
• LogP: 3.35330
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 18
• Rotatable Bond Count: 0
• Exact Mass: 515.78165
• Heavy Atom Count: 25
• Complexity: 145

Purity/Quality:

99%+, ^*data from raw suppliers

Gallium(III) trifluoromethanesulfonate 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 45-36/37/39-25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Ga+3]

Technology Process of Gallium(III) trifluoromethanesulfonate

There total 6 articles about Gallium(III) trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + Gallium trichloride (13450-90-3) → gallium(III) triflate (74974-60-0)

Guidance literature:

In 1,1,2-Trichloro-1,2,2-trifluoroethane; soln. of the components mildly refluxed for 10-12 h; white solid obtained after removal of the solvent; product washed several times with Freon-113 under dry N2; elem. anal.;

DOI:10.1021/ja00216a032

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + gallium(III) bromide (13450-88-9) → gallium(III) triflate (74974-60-0)

Guidance literature:

In 1,1,2-Trichloro-1,2,2-trifluoroethane; soln. of the components mildly refluxed for 10-12 h; white solid obtained after removal of the solvent; product washed several times with Freon-113 under dry N2;

DOI:10.1021/ja00216a032

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + gallium(III) iodide (13450-91-4) → gallium(III) triflate (74974-60-0)

Guidance literature:

In 1,1,2-Trichloro-1,2,2-trifluoroethane; soln. of the components mildly refluxed for 10-12 h; white solid obtained after removal of the solvent; product washed several times with Freon-113 under dry N2;

DOI:10.1021/ja00216a032

upstream raw materials:

trifluorormethanesulfonic acid

gallium

Gallium trichloride

gallium(III) bromide

Refernces

• 1、 Topel, ?nder,Persson, Ingmar,Lundberg, Daniel,Ullstr?m, Ann-Sofi. "On the structure of the N,N′-dimethylpropyleneurea and dimethylsulfoxide solvated gallium(III) and indium(III) ions and bromide complexes in solution and solid state, and the complex formation of the gallium(III) and indium(III) bromide systems in N,N′-dimethylpropyleneurea". . p. 988 - 994. Retrieved 2010.
• 2、 Olah,Farooq,Morteza,Farnia,Olah. "BORON, ALUMINUM, AND GALLIUM TRIS(TRIFLUOROMETHANESULFONATE) (TRIFLATE): EFFECTIVE NEW FRIEDEL-CRAFTS CATALYSTS.". . p. 2560 - 2565. Retrieved 2007/10/02.