Technology Process of (Z) 1-(t-butoxydiphenylsilyloxy) 6-iodo-3-butene
There total 5 articles about (Z) 1-(t-butoxydiphenylsilyloxy) 6-iodo-3-butene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 1) LiNH2/NH3 / 1) hexane, 2) 5h
2: 97 percent / H2 / Ni(OAc)2*4H2O, NaBH4 / ethanol / 0.25 h / 760 Torr
3: 1) MsCl, NEt3, 2) NaI / 1) CH2Cl2, RT, 0.5h, 2) acetone, 2h, reflux
With
lithium amide; ammonia; hydrogen; methanesulfonyl chloride; triethylamine; sodium iodide;
sodium tetrahydroborate; nickel diacetate;
In
ethanol;
DOI:10.1016/S0040-4020(01)96002-8
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 97 percent / H2 / Ni(OAc)2*4H2O, NaBH4 / ethanol / 0.25 h / 760 Torr
2: 1) MsCl, NEt3, 2) NaI / 1) CH2Cl2, RT, 0.5h, 2) acetone, 2h, reflux
With
hydrogen; methanesulfonyl chloride; triethylamine; sodium iodide;
sodium tetrahydroborate; nickel diacetate;
In
ethanol;
DOI:10.1016/S0040-4020(01)96002-8
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 98 percent / imidazole / dimethylformamide / 8 h / Ambient temperature
2: 1) LiNH2/NH3 / 1) hexane, 2) 5h
3: 97 percent / H2 / Ni(OAc)2*4H2O, NaBH4 / ethanol / 0.25 h / 760 Torr
4: 1) MsCl, NEt3, 2) NaI / 1) CH2Cl2, RT, 0.5h, 2) acetone, 2h, reflux
With
1H-imidazole; lithium amide; ammonia; hydrogen; methanesulfonyl chloride; triethylamine; sodium iodide;
sodium tetrahydroborate; nickel diacetate;
In
ethanol; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)96002-8