5-Norbornene-2-endo,3-endo-dimethanol

Base Information

• Chemical Name: 5-Norbornene-2-endo,3-endo-dimethanol
• CAS No.: 699-97-8
• Molecular Formula: C₉H₁₄O₂
• Molecular Weight: 154.209
• European Community (EC) Number: 625-614-1
• Nikkaji Number: J338.414D
• Wikidata: Q106902810
• Mol file: 699-97-8.mol

Synonyms:5-Norbornene-2-endo,3-endo-dimethanol;rel-(1R,2S,3R,4S)-Bicyclo[2.2.1]hept-5-ene-2,3-dimethanol;SCHEMBL5050260;5-Norbornene-2-endo,3-endo-dimethanol, 98%;T72847;5-Norbornene-2-endo,3-endo-dimethanol, >/=98%;(1beta,4beta)-Norborn-5-ene-2alpha,3alpha-dimethanol;(endo,endo)-bicyclo[2.2.1]hept-5-ene-2,3-dimethanol

Chemical Property of 5-Norbornene-2-endo,3-endo-dimethanol

Chemical Property:

• Vapor Pressure: 0.002mmHg at 25°C
• Melting Point: 86 °C
• Refractive Index: 1.537
• Boiling Point: 259.821 °C at 760 mmHg
• Flash Point: 122.714 °C
• PSA: 40.46000
• Density: 1.137 g/cm³
• LogP: 0.40930
• Solubility.: soluble in Methanol
• XLogP3: 0.4
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 154.099379685
• Heavy Atom Count: 11
• Complexity: 158

Purity/Quality:

98% ^*data from raw suppliers

5-Norbornene-2-endo,3-endo-dimethanol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C2C=CC1C(C2CO)CO
• Isomeric SMILES: C1[C@@H]2C=C[C@H]1[C@H]([C@H]2CO)CO

Technology Process of 5-Norbornene-2-endo,3-endo-dimethanol

There total 3 articles about 5-Norbornene-2-endo,3-endo-dimethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ endo-cis-5-Norbornen-2,3-dimethanol (85-39-2,699-95-6,699-96-7,699-97-8,54423-36-8,78037-77-1,79516-58-8,111321-65-4,448922-61-0)

Guidance literature:

exo-cis-Dimethyl-5-norbornen-2,3-dicarboxylat, LiAlH4 / sd. Tetrahydrofuran;

DOI:10.1021/jo01068a028

Reference yield:

→ trans-5-Nrbornen-2,3-dimethanol (85-39-2,699-95-6,699-96-7,699-97-8,54423-36-8,78037-77-1,79516-58-8,111321-65-4,448922-61-0)

Guidance literature:

trans-Dimethyl-5-norbornen-2,3-dicarboxylat, LiAlH4 / Tetrahydrofuran;

DOI:10.1021/jo01068a028

Reference yield:

→ ((1R,2R,4R)-3-Hydroxymethyl-bicyclo[2.2.1]hept-5-en-2-yl)-methanol (85-39-2,699-95-6,699-96-7,699-97-8,54423-36-8,78037-77-1,79516-58-8,111321-65-4,448922-61-0)

Guidance literature:

Diester (3), LiAlH4;

DOI:10.1016/S0040-4039(01)94750-1

Downstream raw materials:

Methanesulfonic acid (2R,3R)-3-methanesulfonyloxymethyl-bicyclo[2.2.1]hept-5-en-2-ylmethyl ester