2,4-Bis(bromomethyl)-1,3,5-triethylbenzene

Base Information

• Chemical Name: 2,4-Bis(bromomethyl)-1,3,5-triethylbenzene
• CAS No.: 190779-61-4
• Molecular Formula: C14H20Br2
• Molecular Weight: 348.121
• DSSTox Substance ID: DTXSID00447850
• Mol file: 190779-61-4.mol

Synonyms:190779-61-4;2,4-BIS(BROMOMETHYL)-1,3,5-TRIETHYLBENZENE;Benzene, 2,4-bis(bromomethyl)-1,3,5-triethyl-;2,4-BIS-(BROMOMETHYL)-1,3,5-TRIETHYLBENZENE;DTXSID00447850;AKOS032947892;FT-0703439;2,4-bis-(bromomethyl)-1,3,5-triethyl benzene;3-CHLORO-2,4-TRIMETHYLENENGLUTACONDIANILHYDROCHLORIDE

Chemical Property of 2,4-Bis(bromomethyl)-1,3,5-triethylbenzene

Chemical Property:

• Vapor Pressure: 0.000149mmHg at 25°C
• Refractive Index: 1.563
• Boiling Point: 342.5 °C at 760 mmHg
• Flash Point: 187.2 °C
• PSA: 0.00000
• Density: 1.41 g/cm³
• LogP: 5.16360
• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 347.99113
• Heavy Atom Count: 16
• Complexity: 175

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC1=CC(=C(C(=C1CBr)CC)CBr)CC

Technology Process of 2,4-Bis(bromomethyl)-1,3,5-triethylbenzene

There total 2 articles about 2,4-Bis(bromomethyl)-1,3,5-triethylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1,3,5-triethylbenzene (102-25-0) → 2,4-bis(bromomethyl)-1,3,5-triethyl benzene (190779-61-4)

Guidance literature:

With hydrogen bromide; In acetic acid; at 80 ℃; for 8h; Inert atmosphere;

DOI:10.1039/c7dt01724c

Reference yield:

1,3,5-triethylbenzene (102-25-0) → 2,4-bis(bromomethyl)-1,3,5-triethyl benzene (190779-61-4)

Guidance literature:

1,3,5-triethylbenzene; paraformaldehyde; With zinc;

With hydrogen bromide; acetic acid; at 135 ℃; Further stages.;

DOI:10.1039/b102480a

Reference yield: 98.0%

1,4,7,10-tetraazacyclododecan (294-90-6) + 2,4-bis(bromomethyl)-1,3,5-triethyl benzene (190779-61-4) → 1,1′-((2,4,6-triethyl-1,3-phenylene)bis(methylene))bis(1,4,7,10-tetraazacyclo-dodecane)

Guidance literature:

With triethylamine; In chloroform; at 20 ℃; for 121.5h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.8b00539

upstream raw materials:

formaldehyd

1,3,5-triethylbenzene

Downstream raw materials:

1,3-bis(1-methylimidazole-2-thio)-2,4,6-triethylbenzene

1,3,5-tris(azidomethyl)-2,4,6-triethylbenzene

1,3,5-triethyl-2,4,6-tris(aminomethyl)benzene

1-[[(1,1-dimethylethoxy)carbonyl]aminomethyl]-3,5-bis(aminomethyl)-2,4,6-triethylbenzene

Refernces

• 1、 Esteves, Catarina V.,Esteban-Gómez, David,Platas-Iglesias, Carlos,Tripier, Rapha?l,Delgado, Rita. "Steric Effects on the Binding of Phosphate and Polyphosphate Anions by Zinc(II) and Copper(II) Dinuclear Complexes of m-Xylyl-bis-cyclen". . p. 6466 - 6478. Retrieved 2018/06/14.
• 2、 Capitan-Vallvey, Luis Fermin,Arroyo-Guerrero, Eduardo,Fernandez-Ramos, Maria Dolores,Santoyo-Gonzalez. "Disposable receptor-based optical sensor for nitrate". . p. 4459 - 4466. Retrieved 2008/02/02.