trans-1,3-dimethylcyclohexane

Base Information

• Chemical Name: trans-1,3-dimethylcyclohexane
• CAS No.: 69685-68-3
• Molecular Formula: C₈H₁₆
• Molecular Weight: 112.215
• Mol file: 69685-68-3.mol

Synonyms:trans-1,3-dimethylcyclohexane

Chemical Property of trans-1,3-dimethylcyclohexane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-1,3-dimethylcyclohexane

There total 79 articles about trans-1,3-dimethylcyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

m-xylene (108-38-3,104809-90-7) → 1,3-dimethylcyclohexane (638-04-0,2207-03-6,69685-67-2,69685-68-3,129939-72-6,129939-73-7,591-21-9)

Guidance literature:

With hydrogen; [(norbornadiene)rhodium(I)chloride]2; phosphinated polydiacetylene; In n-heptane; at 30 ℃; for 1.5h; under 60800 Torr;

DOI:10.1246/cl.1982.603

Reference yield: 80.0%

1,3-dimethylcyclohexene (2808-76-6) → 1,3-dimethylcyclohexane (638-04-0,2207-03-6,69685-67-2,69685-68-3,129939-72-6,129939-73-7,591-21-9)

Guidance literature:

With hydrogen; 1,5-hexadienerhodium(I)-chloride dimer; In various solvent(s); for 8h; Ambient temperature; pH=7.6;

Reference yield:

toluene (108-88-3,15644-74-3,16713-13-6) → biphenyl (92-52-4,1594-86-1) + methyl-cyclopentane (96-37-7) + cyclohexane (110-82-7,25012-93-5) + ethyl-cyclohexane (1678-91-7) + 1,3-dimethylcyclohexane (638-04-0,2207-03-6,69685-67-2,69685-68-3,129939-72-6,129939-73-7,591-21-9) + 1,3,5-trimethylcyclohexane (1839-63-0) + para-xylene (106-42-3) + ethylbenzene (100-41-4,27536-89-6) + methyl cyclohexane (82166-21-0) + m-xylene (108-38-3,104809-90-7) + 1,3,5-trimethyl-benzene (108-67-8) + isoprene (78-79-5,9003-31-0) + 1,4 dimethylcyclohexane (589-90-2) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

With Ni-doped silica; water; hydrogen; at 119.84 ℃; Reagent/catalyst; Catalytic behavior;

DOI:10.1016/j.apcata.2019.117374

upstream raw materials:

3,5-dimethyl-2-cyclohexen-1-one

ethene

cyclohexane

2-ethyl-1-methylcyclopentane

Downstream raw materials:

1,2-di-m-tolylethane

perfluoro-1,3-dimethylcyclohexane

optically inactive 1.3-dimethyl-cyclohexanediol-(1.3)

1,3-dimethyl-1-nitro-cyclohexane

Refernces

• 1、 Chatterjee, Basujit,Kalsi, Deepti,Kaithal, Akash,Bordet, Alexis,Leitner, Walter,Gunanathan, Chidambaram. "One-pot dual catalysis for the hydrogenation of heteroarenes and arenes". . p. 5163 - 5170. Retrieved 2020/09/07.
• 2、 Bordet, Alexis,Emondts, Meike,Kacem, Souha,Leitner, Walter. "Selective hydrogenation of fluorinated arenes using rhodium nanoparticles on molecularly modified silica". . p. 8120 - 8126. Retrieved 2020/12/28.