Perfluorononanoyl chloride

Base Information

• Chemical Name: Perfluorononanoyl chloride
• CAS No.: 52447-23-1
• Molecular Formula: C9Cl F17 O
• Molecular Weight: 482.524
• Hs Code.: 2915900090
• European Community (EC) Number: 623-759-5
• DSSTox Substance ID: DTXSID00379925
• Nikkaji Number: J1.797.141G
• Wikidata: Q81985841
• Mol file: 52447-23-1.mol

Synonyms:Perfluorononanoyl chloride;52447-23-1;2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononanoyl Chloride;Heptadecafluorononanoyl chloride;SCHEMBL811565;perfluoropelargonic acid chloride;DTXSID00379925;MPWXHQITWLFMQM-UHFFFAOYSA-N;Heptadecafluorononanoic acid chloride;MFCD00153255;AKOS015852734;FS-4441;Heptadecafluorononanoyl chloride, >=98.0%;FT-0676340;A829090;2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecakis(fluoranyl)nonanoyl chloride

Chemical Property of Perfluorononanoyl chloride

Chemical Property:

• Vapor Pressure: 3.12mmHg at 25°C
• Boiling Point: 154.8°Cat760mmHg
• Flash Point: 47.4°C
• PSA: 17.07000
• Density: 1.731g/cm³
• LogP: 5.76120
• XLogP3: 6.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 18
• Rotatable Bond Count: 7
• Exact Mass: 481.9366211
• Heavy Atom Count: 28
• Complexity: 617

Purity/Quality:

98%min ^*data from raw suppliers

Perfluorononanoyl chloride 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,C
• Hazard Codes: Xn,C
• Statements: 22-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)Cl

Technology Process of Perfluorononanoyl chloride

There total 2 articles about Perfluorononanoyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium heptadecafluorononanoate → heptadecafluorononanic acid chloride (52447-23-1)

Guidance literature:

With 1-methyl-1H-imidazole; phosphorus pentachloride; tetrabutylammomium bromide; In toluene; at 35 ℃; for 2.5h;

Reference yield:

perfluorononanoic acid (375-95-1) → heptadecafluorononanic acid chloride (52447-23-1)

Guidance literature:

With pyridine; thionyl chloride; for 2h; Heating;

DOI:10.1016/S0022-1139(00)85181-7

Reference yield: 88.0%

C111H124O19 + heptadecafluorononanic acid chloride (52447-23-1) → C120H123F17O20

Guidance literature:

With 4-methyl-morpholine; In tetrahydrofuran; at 50 - 55 ℃; for 6h; Inert atmosphere;

DOI:10.1134/S1070427214050218

upstream raw materials:

perfluorononanoic acid

Downstream raw materials:

perfluorononanoic acid methyl ester

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro-1-phenylnonan-1-one

2-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-Heptadecafluoro-nonanoyl)-cyclohexanone

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro-N-<(4-cyanomethyl)phenyl>nonanamide

Refernces

• 1、 Czarnocki, Stefan,Frankfurter, René,Grela, Karol,Kajetanowicz, Anna,Kirschning, Andreas,Kopcha, William,Monsigny, Louis,Sienkiewicz, Micha?,Solodenko, Wladimir,Vogt, Carla. "Ruthenium Complex Bearing a Hydroxy Group Functionalised N-Heterocyclic Carbene Ligand – A Universal Platform for Synthesis of Tagged and Immobilised Catalysts for Olefin Metathesis". supporting information. p. 6424 - 6434. Retrieved 2021/12/08.
• 2、 Granados, Alejandro,De Rossi, Rita H.. "Multiple pathways in cyclodextrin-catalyzed hydrolysis of perfluoroalkylamides". . p. 3690 - 3696. Retrieved 2007/10/02.