phenyl trifluoromethyl sulfilimine

Base Information

• Chemical Name: phenyl trifluoromethyl sulfilimine
• CAS No.: 1260111-65-6
• Molecular Formula: C₇H₆F₃NS
• Molecular Weight: 193.193
• Mol file: 1260111-65-6.mol

Synonyms:phenyl trifluoromethyl sulfilimine

Chemical Property of phenyl trifluoromethyl sulfilimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl trifluoromethyl sulfilimine

There total 1 articles about phenyl trifluoromethyl sulfilimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

phenyl trifluoromethyl sulfoxide (703-18-4) → phenyl trifluoromethyl sulfilimine (1260111-65-6)

Guidance literature:

phenyl trifluoromethyl sulfoxide; With trifluoromethylsulfonic anhydride; acetonitrile; at -15 ℃; for 24h;

With propylamine; In dichloromethane; at -15 - 20 ℃; for 24h;

DOI:10.1002/adsc.201000494

Reference yield: 100.0%

phenyl trifluoromethyl sulfilimine (1260111-65-6) + p-toluenesulfonyl chloride (98-59-9) → phenyl N-p-toluenesulfonyl trifluoromethyl sulfilimine (1260112-12-6)

Guidance literature:

With pyridine; In dichloromethane; at 20 ℃; Reflux;

DOI:10.1002/adsc.201000494

Reference yield: 84.0%

trifluoromethylsulfonic anhydride (358-23-6) + phenyl trifluoromethyl sulfilimine (1260111-65-6) → phenyl N-(trifluoromethanesulfonyl) trifluoromethyl sulfilimine (95970-27-7)

Guidance literature:

With pyridine; In dichloromethane; at 0 - 20 ℃;

DOI:10.1002/adsc.201000494

upstream raw materials:

phenyl trifluoromethyl sulfoxide

Downstream raw materials:

N-nitro phenyl trifluoromethyl sulfilimine

N-cyano phenyl trifluoromethyl sulfilimine

phenyl N-(trifluoromethanesulfonyl) trifluoromethyl sulfilimine

N-tert-butoxycarbonyl phenyl trifluoromethyl sulfilimine

Refernces