bis(4-chlorophenyl)(4-methylphenyl)-selenonium chloride

Base Information

• Chemical Name: bis(4-chlorophenyl)(4-methylphenyl)-selenonium chloride
• CAS No.: 127356-68-7
• Molecular Formula: C₁₉H₁₅Cl₃Se
• Molecular Weight: 428.647
• Mol file: 127356-68-7.mol

Synonyms:bis(4-chlorophenyl)(4-methylphenyl)-selenonium chloride

Chemical Property of bis(4-chlorophenyl)(4-methylphenyl)-selenonium chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(4-chlorophenyl)(4-methylphenyl)-selenonium chloride

There total 4 articles about bis(4-chlorophenyl)(4-methylphenyl)-selenonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

λ4-bis(4-chlorophenyl)dichloroselane (125556-35-6) + toluene (108-88-3,15644-74-3,16713-13-6) → bis(4-chlorophenyl)(4-methylphenyl)-selenonium chloride (127356-68-7)

Guidance literature:

With antimonypentachloride; at 10 ℃; for 4h;

DOI:10.1021/jo00300a030

Reference yield:

toluene (108-88-3,15644-74-3,16713-13-6) → para-chlorotoluene (106-43-4) + 2-methylchlorobenzene (95-49-8) + bis(4-chlorophenyl)(4-methylphenyl)-selenonium chloride (127356-68-7)

Guidance literature:

With chlorine; aluminium trichloride; bis(4-chlorophenyl)selenide; at -30 - 70 ℃; for 4h; Mechanism; Product distribution; other lewis acids (FeCl₃, SbCl₃, SbF₃, SbCl₅) or lewis acids without bis(4-chlorophenyl)selenide;

DOI:10.1021/jo00300a030

Reference yield:

bis(4-chlorophenyl)selenide (58235-79-3) → bis(4-chlorophenyl)(4-methylphenyl)-selenonium chloride (127356-68-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 71 percent / Cl₂ / CCl₄ / 1 h / -20 - -15 °C

2: 58 percent / SbCl₅ / 4 h / 10 °C

With antimonypentachloride; chlorine; In tetrachloromethane;

DOI:10.1021/jo00300a030

upstream raw materials:

λ⁴-bis(4-chlorophenyl)dichloroselane

toluene

bis(4-chlorophenyl)selenide

4-chloro-aniline

Downstream raw materials:

para-chlorotoluene

2-methylchlorobenzene

C₇⁽²⁾H₇Cl

C₇⁽²⁾H₇Cl

Refernces