Bis(4-biphenylyl)amine

Base Information

• Chemical Name: Bis(4-biphenylyl)amine
• CAS No.: 102113-98-4
• Molecular Formula: C24H19N
• Molecular Weight: 321.422
• Hs Code.: 2921499090
• Mol file: 102113-98-4.mol

Synonyms:Bis(4-biphenylyl)amine(6CI,7CI);N,N-Bis(4-phenylphenyl)amine;

Chemical Property of Bis(4-biphenylyl)amine

Chemical Property:

• Vapor Pressure: 0-0Pa at 20-50℃
• Melting Point: 209 °C
• Boiling Point: 507 °C at 760 mmHg
• PKA: 0.67±0.40(Predicted)
• Flash Point: 281.7 °C
• PSA: 12.03000
• Density: 1.123 g/cm³
• LogP: 6.83720
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Solubility.: Acetonitrile (Slightly), Chloroform (Slightly), DMSO (Slightly)

Purity/Quality:

99%+ ^*data from raw suppliers

Bis-Biphenyl-4-yl-amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Bis(4-biphenylyl)amine can be used as organic synthesis intermediate and pharmaceutical intermediate, mainly in laboratory research and development process and chemical production process.

Technology Process of Bis(4-biphenylyl)amine

There total 22 articles about Bis(4-biphenylyl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

4-bromo-1,1'-biphenyl (92-66-0) + 4-phenylalanine (92-67-1) → bis(biphenyl-4-yl)amine (102113-98-4)

Guidance literature:

With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In toluene; at 110 ℃; for 12h;

Reference yield: 95.0%

N,N-bis(4-biphenyl)acetamide (13020-85-4) → bis(biphenyl-4-yl)amine (102113-98-4)

Guidance literature:

With sodium hydroxide; In ethanol; for 10h; Reagent/catalyst; Reflux;

Reference yield: 94.0%

N,N-di-(4-biphenyl)benzylamine (462631-32-9) → bis(biphenyl-4-yl)amine (102113-98-4)

Guidance literature:

With hydrogen; palladium on activated carbon; In ethanol; chloroform; at 20 ℃; for 30h;

upstream raw materials:

4-iodo-biphenyl

4-phenylacetanilide

4-phenylalanine

tetrachloromethane

Downstream raw materials:

tris(p-biphenyl)amine

tetrakis-biphenyl-4-yl-hydrazine

N-([1′,1′-biphenyl]-4-yl)-N-(4-bromophenyl)-[1,1′-biphenyl]-4-amine

C₆₄H₄₆N₂

Refernces

• 1、 Joung, Kuk Soung,Kim, Kyu Sung,Kim, Seung Uk,Tak, So Hyun,Yu, Jae-Woong. "Effect of arylamino-carbazole containing hole transport materials on the device performance and lifetime of OLED". . . Retrieved 2021/11/16.
• 2、 -. "Preparation method of bis (4-biphenyl) amine". Paragraph 0034; 0053-0068. . Retrieved 2022/03/27.