ethyl N-phenylbenzenecarboximidoate

Base Information

• Chemical Name: ethyl N-phenylbenzenecarboximidoate
• CAS No.: 6780-41-2
• Molecular Formula: C15H15 N O
• Molecular Weight: 225.29
• Mol file: 6780-41-2.mol

Synonyms:Benzimidic acid, N-phenyl-, ethyl ester (7CI,8CI); NSC155344

Chemical Property of ethyl N-phenylbenzenecarboximidoate

Chemical Property:

• Vapor Pressure: 0.000359mmHg at 25°C
• Boiling Point: 328.6°Cat760mmHg
• Flash Point: 124.7°C
• Density: 0.99g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ethyl N-phenylbenzenecarboximidoate

There total 18 articles about ethyl N-phenylbenzenecarboximidoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

Fe3(μ-NC6H5)2(CO)8(C(OC2H5)C6H5) (94404-84-9) → Fe3(μ3-NPh)(CO)10 + N-Phenyl-benzimidic acid ethyl ester (6780-41-2)

Guidance literature:

With CO; In not given; eposure of Fe-compd. to 1 atm CO (22°C, 6 days);; yield detn. of org. product by proton NMR;;

DOI:10.1021/ja00289a049

Reference yield: 67.0%

ethyl 1-(phenylimino)phenylmethanesulfenate (96995-37-8) → N-Phenyl-benzimidic acid ethyl ester (6780-41-2)

Guidance literature:

With tributylphosphine; In dichloromethane; for 12h; Ambient temperature;

Reference yield:

benzoic acid ethyl ester (93-89-0,99341-95-4) + erythro-1,2-dibromo-1-phenylpropylphosphonate → methylphosphate (812-00-0) + methyl N-phenylphosphoramidate (75040-62-9) + N-Phenyl-benzimidic acid ethyl ester (6780-41-2)

Guidance literature:

With 2,2,6,6-tetramethyl-piperidine; aniline; In 1,2-dimethoxyethane; for 120h;

DOI:10.1021/ja00533a027

upstream raw materials:

ethanol

benzophenone-(O-benzenesulfonyl oxime )

sodium ethanolate

N-phenyl-benzimidoyl chloride

Downstream raw materials:

2-Hydroxy-2,4,5-triphenyl-3(2H)-furanone

benzoic acid ethyl ester

aniline

chloroethane

Refernces

• 1、 Lenz, Bodo G.,Zwanenburg, Binne. "α-Imino sulfenates and α-imino sulfoxides via electrophilic alkylation of amino sulfines (thioamide S-oxides)". . p. 342 - 347. Retrieved 2007/10/02.
• 2、 Satterthwait, Arnold C.,Westheimer, F. H.. "Monomeric Methyl Metaphosphate: Reactions with Carbonyl Groups". . p. 4464 - 4472. Retrieved 2007/10/02.