N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine

Base Information

• Chemical Name: N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine
• CAS No.: 863487-48-3
• Molecular Formula: C₂₈H₂₂N₂
• Molecular Weight: 386.496
• Mol file: 863487-48-3.mol

Synonyms:N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine

Chemical Property of N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine

There total 1 articles about N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

2-chloro-4-methylquinoline (634-47-9) + 4-(diphenylamino)phenyl boronic acid (201802-67-7) → N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine (863487-48-3)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran; water; at 80 ℃; for 24h; Inert atmosphere;

DOI:10.1080/15421406.2017.1350041

Reference yield: 65.0%

N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine (863487-48-3) + iridium (III) chloride (10025-83-9) + acetylacetone (123-54-6,81235-32-7) → Ir(N-(4-(4-methylquinolin-2-yl)-N-phenylbenzenamine(1-))2(acetylacetonate) (863487-42-7)

Guidance literature:

With sodium carbonate; In 2-methoxy-ethanol; water; under N2 atm. mixt. quinoline, IrCl3, MeOCH2CH2OH and water was heated at reflux for 12 h, ppt. was filtered, washed with MeOH, Et2O and hexane,dried, suspended in MeOCH2CH2OH, treated with acetylacetone and Na2CO3, heated at 80°C for 8 h; ppt. was filtered, washed with water, MeOH and Et2O, dried and dissolvedin CH2Cl2, chromy. on silica (hexane-CH2Cl2 3:2), recrystn. from CH2Cl2 -hexane; elem. anal.;

DOI:10.1021/ic050385s

Reference yield:

N-(4-(4-methylquinolin-2-yl)phenyl)-N-phenylbenzenamine (863487-48-3) + iridium(III) chloride monohydrate → [(4-(4-methylquinolin-2-yl)diphenylaniline)2IrCl]2

Guidance literature:

In 2-ethoxy-ethanol; water; at 135 ℃; for 27h; Inert atmosphere;

DOI:10.1080/15421406.2017.1350041

upstream raw materials:

2-chloro-4-methylquinoline

4-(diphenylamino)phenyl boronic acid

Downstream raw materials:

Ir(N-(4-(4-methylquinolin-2-yl)-N-phenylbenzenamine^(1-))2(acetylacetonate)

Refernces