Lithium, 2-propenyl-(9CI)

Base Information

• Chemical Name: Lithium, 2-propenyl-(9CI)
• CAS No.: 3052-45-7
• Molecular Formula: C3H5 Li
• Molecular Weight: 48.0137
• Mol file: 3052-45-7.mol

Synonyms:Lithium,allyl- (6CI,7CI,8CI); 1-Propene, lithium complex; 2-Propenyllithium;Allyllithium

Chemical Property of Lithium, 2-propenyl-(9CI)

Chemical Property:

• Boiling Point: 59.6°C
• PSA: 0.00000
• LogP: 1.14000

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3:
• Safety Statements: Ignites on contact with air. See also LITHIUM COMPOUNDS.:;"> LITHIUM COMPOUNDS." target="_blank">Ignites on contact with air. See also LITHIUM COMPOUNDS.:

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Lithium, 2-propenyl-(9CI)

There total 11 articles about Lithium, 2-propenyl-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

allytriphenyltin (76-63-1) → allyllithium (3052-45-7)

Guidance literature:

With phenyllithium; In diethyl ether; at -30 - -20 ℃; for 10h; Large scale;

Reference yield:

tetraallyl tin (7393-43-3) + phenyllithium (591-51-5) → tetraphenyltin(IV) (595-90-4) + allyllithium (3052-45-7)

Guidance literature:

In diethyl ether;

Reference yield:

allyltributylstanane (24850-33-7) → allyllithium (3052-45-7)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tetlet.2012.10.092

upstream raw materials:

allyl phenyl ether

tetraallyl tin

allytriphenyltin

trimethyl(allyl)stannane

Downstream raw materials:

oct-1-ene

2,4-dimethyl-6-hepten-4-ol

allyltriphenylsilane

1-Allyl-2-ethynyl-cyclohexane

Refernces

• 1、 Johnson et al.. "". . p. 1306. Retrieved 1961.
• 2、 Horikawa, Yasuo,Takeda, Takeshi. "The allyl group exchange reaction between tri( substituted allyl) stannyllithium and ( substituted allyl) lithium". . p. 99 - 104. Retrieved 1996.
• 3、 -. "The continuous reaction device and method of using the continuous composite (by machine translation)". Paragraph 0181. . Retrieved 2017/01/02.
• 4、 Dumoulin, David,Lebrun, Stephane,Couture, Axel,Deniau, Eric,Grandclaudon, Pierre. "First asymmetric synthesis of boehmeriasin A". experimental part. p. 1943 - 1950. Retrieved 2010/06/13.