lithium pentafluorobenzenesulfinate

Base Information

• Chemical Name: lithium pentafluorobenzenesulfinate
• CAS No.: 36649-96-4
• Molecular Formula: C₆F₅O₂S*Li
• Molecular Weight: 238.064
• Mol file: 36649-96-4.mol

Synonyms:lithium pentafluorobenzenesulfinate

Chemical Property of lithium pentafluorobenzenesulfinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of lithium pentafluorobenzenesulfinate

There total 1 articles about lithium pentafluorobenzenesulfinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + bromopentafluorobenzene (344-04-7) → lithium pentafluorobenzenesulfinate (36649-96-4) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3)

Guidance literature:

In hexane; at -64°C, for 1.5 h, then at -70. degree.C, introduction of SO2 under 3 h, standing for 1 h;

DOI:10.1016/S0022-1139(00)83114-0

Reference yield: 92.0%

lithium pentafluorobenzenesulfinate (36649-96-4) + pentafluorophenylmercury chloride (941-78-6) → bis(pentafluorophenyl)mercury(II) (973-17-1)

Guidance literature:

In water; tert-butyl alcohol; 25°C, 10 min, ratio of LiOS(O)C6F5 and HgCl2 = 1.3:0.35;

DOI:10.1016/S0022-1139(00)81712-1 DOI:10.1016/S0022-1139(00)82867-5

Reference yield: 89.0%

lithium pentafluorobenzenesulfinate (36649-96-4) + sulfur tetrafluoride (7783-60-0) → pentafluorobenzenesulfinyl fluoride (36649-98-6)

Guidance literature:

In further solvent(s); solvent: CFCl3, 50°C, 2 h;

DOI:10.1016/S0022-1139(00)83114-0

upstream raw materials:

n-butyllithium

bromopentafluorobenzene

Downstream raw materials:

pentafluorobenzenesulfinyl chloride

pentafluorobenzenesulfinyl fluoride

bis(pentafluorophenyl)mercury(II)

bis-(pentafluoro phenyl) thallium acetate