10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole

Base Information

• Chemical Name: 10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole
• CAS No.: 1315509-04-6
• Molecular Formula: C₃₅H₂₉N
• Molecular Weight: 463.622
• Mol file: 1315509-04-6.mol

Synonyms:10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole

Chemical Property of 10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole

There total 4 articles about 10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole (1315509-03-5) + 1-bromo-4-(2,2-diphenylvinyl)benzene (18648-66-3) → 10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole (1315509-04-6)

Guidance literature:

With tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate; In 5,5-dimethyl-1,3-cyclohexadiene; at 120 ℃; for 16h;

DOI:10.1016/j.dyepig.2011.02.009

Reference yield:

cyclopentanone (120-92-3) → 10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole (1315509-04-6)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium acetate; acetic acid / dichloromethane; water / 2 h / Reflux

2: sodium tetrahydroborate; acetic acid / 24 h / 20 °C

3: tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate / 5,5-dimethyl-1,3-cyclohexadiene / 16 h / 120 °C

With sodium tetrahydroborate; tri-tert-butyl phosphine; potassium tert-butylate; sodium acetate; palladium diacetate; acetic acid; In 5,5-dimethyl-1,3-cyclohexadiene; dichloromethane; water;

DOI:10.1016/j.dyepig.2011.02.009

Reference yield:

7,8,9,10-tetrahydrobenzo[g]cyclopenta[b]indole (7234-76-6) → 10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole (1315509-04-6)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium tetrahydroborate; acetic acid / 24 h / 20 °C

2: tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate / 5,5-dimethyl-1,3-cyclohexadiene / 16 h / 120 °C

With sodium tetrahydroborate; tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate; acetic acid; In 5,5-dimethyl-1,3-cyclohexadiene;

DOI:10.1016/j.dyepig.2011.02.009

upstream raw materials:

7,8,9,10-tetrahydrobenzo[g]cyclopenta[b]indole

6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole

1-bromo-4-(2,2-diphenylvinyl)benzene

cyclopentanone

Downstream raw materials:

10-[4-(2,2-diphenylethenyl)phenyl]-6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole-5-carbaldehyde

Refernces