DI-N-PROPYLZINC

Base Information

• Chemical Name: DI-N-PROPYLZINC
• CAS No.: 628-91-1
• Molecular Formula: C₆H₁₄Zn
• Molecular Weight: 151.567
• Mol file: 628-91-1.mol

Synonyms:Dipropylzinc;DI-N-PROPYLZINC

Chemical Property of DI-N-PROPYLZINC

Chemical Property:

• Melting Point: 25°C
• Boiling Point: 148°C
• PSA: 0.00000
• Density: 1.0800
• LogP: 2.72550

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DI-N-PROPYLZINC

There total 1 articles about DI-N-PROPYLZINC which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.3%

1-iodo-propane (107-08-4) → propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + propane (74-98-6) + di-n-propyl zinc (628-91-1)

Guidance literature:

With iron; zinc; at 200 ℃; for 1h; Product distribution; Zn, 300 deg C;

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + di-n-propyl zinc (628-91-1) → 2,4,6-trimethyl-nonane (62184-10-5) + 2,4,6,8-tetramethylundecane + 2,4,6,8,10-pentamethyltridecane (1203794-43-7) + 2,4,6,8,10,12-hexamethylpentadecane (1203794-44-8) + 2,4,6,8,10,12,14-heptamethylheptadecane (1297272-97-9) + 2,4,6,8,10,12,14,16-octamethylnonadecane (1297272-98-0) + C30H62 + C21H44

Guidance literature:

propene; di-n-propyl zinc; With dichloro[(η⁵-2,4-cyclopentadien-1-ylidene)(diphenylmethylene)[(5a,5b,11a,12,12a-η)-1,2,3,4,7,8,9,10-octahydro-1,1,4,4,7,7,10,10-octamethyl-12H-dibenzo[b,h]fluoren-12-ylidene]]zirconium; In toluene; at 10 ℃; for 16h; under 3000.3 Torr; Autoclave; Inert atmosphere;

With hydrogenchloride; In water; toluene; Temperature; Inert atmosphere;

DOI:10.1002/anie.201804711

Reference yield:

trichlorosilane (10025-78-2) + di-n-propyl zinc (628-91-1) → triethylsilane (617-86-7) + tetrapropylsilane (994-66-1)

Guidance literature:

In neat (no solvent); SiHCl3 and Zn(C3H7)2 at 150°C;;

upstream raw materials:

1-iodo-propane

Downstream raw materials:

2,2-dimethylpentane

3,3-dimethylhexane

n-heptan1ol

4-decanol

Refernces