Di-tert-butyl diperoxyoxalate

Base Information

• Chemical Name: Di-tert-butyl diperoxyoxalate
• CAS No.: 14666-77-4
• Molecular Formula: C10H18 O6
• Molecular Weight: 234.249
• Mol file: 14666-77-4.mol

Synonyms:Peroxydicarbonicacid, bis(1,1-dimethylethyl) ester (9CI); Peroxydicarbonic acid, di-tert-butylester (7CI,8CI); Di-tert-butyl peroxydicarbonate

Chemical Property of Di-tert-butyl diperoxyoxalate

Chemical Property:

• Refractive Index: 1.4390 (estimate)
• Boiling Point: 296.56°C (rough estimate)
• PSA: 71.06000
• Density: 1.1351 (rough estimate)
• LogP: 2.80480

Purity/Quality:

99% ^*data from raw suppliers

Di-tert-butylPeroxydicarbonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Di-tert-butyl Peroxydicarbonate acts as a catalyst in the polymerization of vinyl monomers.

Technology Process of Di-tert-butyl diperoxyoxalate

There total 1 articles about Di-tert-butyl diperoxyoxalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(tert-butoxycarbonyloxyimino)-2-phenylacetonitrile (74651-77-7) → di-t-butyl peroxydicarbonate (14666-77-4)

Guidance literature:

With perhydrodibenzo-18-crown-6; potassium hydroxide; dihydrogen peroxide; In tetrahydrofuran; at 20 ℃; for 5h; Yield given;

DOI:10.1246/bcsj.58.2207

Reference yield: 46.4%

D-N-carbamoyl-4-[(cis-2,6-dimethyl-1-piperidyl)methyl]phenylalanine (934200-85-8) + di-t-butyl peroxydicarbonate (14666-77-4) → D-N-Boc-4-[(cis-2,6-dimethyl-1-piperidyl)methyl]phenylalanine (934200-87-0)

Guidance literature:

D-N-carbamoyl-4-[(cis-2,6-dimethyl-1-piperidyl)methyl]phenylalanine; With sulfuric acid; sodium nitrite; In water; at 0 - 20 ℃; for 4h;

di-t-butyl peroxydicarbonate; With sodium hydroxide; In water; at 20 ℃; for 13h; pH=9.98;

Reference yield:

Isopropylbenzene (98-82-8) + di-t-butyl peroxydicarbonate (14666-77-4) → dicumene (1889-67-4) + t-butyl α,α-dimethylbenzyl carbonate + tert-butyl alcohol (75-65-0)

Guidance literature:

at 50 ℃; Rate constant; Thermodynamic data; Mechanism; other temperature (40, 60 70 deg C), ΔH^*, ΔS^*, Arrhenius plot;

DOI:10.1246/bcsj.58.2207

upstream raw materials:

2-(tert-butoxycarbonyloxyimino)-2-phenylacetonitrile

Downstream raw materials:

dicumene

tert-butyl alcohol

tert-butyl methyl(3-nitrobenzyl)carbamate

D-N-Boc-4-[(cis-2,6-dimethyl-1-piperidyl)methyl]phenylalanine

Refernces