NICKEL ANTIMONIDE

Base Information

• Chemical Name: NICKEL ANTIMONIDE
• CAS No.: 12035-52-8
• Deprecated CAS: 73482-18-5
• Molecular Formula: NiSb
• Molecular Weight: 180.44
• European Community (EC) Number: 234-827-5
• UN Number: 3077
• DSSTox Substance ID: DTXSID801009934
• Mol file: 12035-52-8.mol

Synonyms:antimony,compd.withnickel(1:1);NICKEL ANTIMONIDE;antimony, compound with nickel (1:1);Nickelantimonide,99.5%(metalsbasisexcludingCo),Co0.1-1%

Chemical Property of NICKEL ANTIMONIDE

Chemical Property:

• Melting Point: 1147°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.00000
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 178.83915
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Ni+3].[Sb]

Technology Process of NICKEL ANTIMONIDE

There total 21 articles about NICKEL ANTIMONIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

sodium antimonide + nickel dichloride (83864-14-6) → nickel antimonide (12035-52-8,12125-61-0,12503-49-0)

Guidance literature:

In ammonia; byproducts: NaCl, Ni; NH3 (liquid); from NiCl2 and Na3Sb in molar ratio 3:2 by stirring at room temp. in liq. NH3 for 36 h; trituration with water and CS2; annealing at 250-300°C for 48 h; powder XRD, SEM/EDXA, Raman-, IR-spectroscopies;

DOI:10.1021/ic010648s

Reference yield: 75.0%

sodium antimonide + nickel dibromide (13462-88-9) → nickel antimonide (12035-52-8,12125-61-0,12503-49-0)

Guidance literature:

In toluene; byproducts: NaBr, Ni; under N2; toluene added to powdered Na3Sb, powdered NiBr2 added under stirring, ratio of Ni salt/Na pnictide = 3:2, heated at reflux for 48 h under stirring; slurry was allowed to settle, toluene syringed off, solid washed subsequently with ethanol, water, and ethanol, annealed at 500°C for 48 h;

DOI:10.1016/S0277-5387(00)00323-5

Reference yield:

antimony (7440-36-0) + nickel dichloride (83864-14-6) → NiSb, γ (12035-52-8,12125-61-0,12503-49-0) + nickel (7440-02-0)

Guidance literature:

With KBH₄; In ethylenediamine; Sonication; Sb, NiCl2, KBH4 and ethylenediamine ultrasonically mixed, heated at 140°C for 24 h; detd. by X-ray powder diffraction;

DOI:10.1006/jssc.2000.8889

upstream raw materials:

antimony

nickel

antimony(III) chloride

nickel dichloride

Refernces

• 1、 Lomnytska,Berezovets. "Phase relations in the Nb-Ni-Sb system". . p. 1166 - 1171. Retrieved 2005.
• 2、 Kift, Rebecca L.,Prior, Timothy J.. "Reductive synthesis of metal antimonides". . p. 428 - 433. Retrieved 2010.
• 3、 Du, Ke-Zhao,Feng, Mei-Ling,Li, Long-Hua,Hu, Bing,Ma, Zu-Ju,Wang, Peng,Li, Jian-Rong,Wang, Yu-Long,Zou, Guo-Dong,Huang, Xiao-Ying. "2Sb18S29: A novel three-dimensional framework thioantimonate(III) templated by [Ni(phen)3] complexes". . p. 3926 - 3928. Retrieved 2012.
• 4、 Lomnytska,Pavliv. "Phase equilibria in the V-Ni-Sb system". . p. 608 - 613. Retrieved 2007.
• 5、 Teichert, Johannes,Heise, Martin,Chang, Jen-Hui,Ruck, Michael. "Refinement of the Microwave-Assisted Polyol Process for the Low-Temperature Synthesis of Intermetallic Nanoparticles". . p. 4930 - 4938. Retrieved 2017.
• 6、 Carmalt, Claire J.,Morrison, Daniel E.,Parkin, Ivan P.. "Liquid-mediated metathetical synthesis of binary and ternary transition-metal pnictides". . p. 829 - 833. Retrieved 2000.
• 7、 Ogarev,Aitkhozhin,Temirov,Palkina,Shchamkhalov,Marenkin. "Bridgman growth of NiSb single crystals". . p. 1162 - 1165. Retrieved 2005.
• 8、 Zeng, Lingmin,Tan, Lizhen. "The 773 K isothermal section of Er-Ni-Sb phase diagram". . p. 197 - 199. Retrieved 2002.
• 9、 Tan, Xiaoming,Su, Xianli,Yan, Yonggao,Uher, Ctirad,Zhang, Qingjie,Tang, Xinfeng. "New criteria for the applicability of combustion synthesis: The investigation of thermodynamic and kinetic processes for binary Chemical Reactions". supporting information. . Retrieved 2021/01/07.