Lithium,(2,3,4,5,6-pentafluorophenyl)-

Base Information

• Chemical Name: Lithium,(2,3,4,5,6-pentafluorophenyl)-
• CAS No.: 1076-44-4
• Molecular Formula: C6F5 Li
• Molecular Weight: 173.999
• Mol file: 1076-44-4.mol

Synonyms:Lithium,(pentafluorophenyl)- (7CI,8CI,9CI); Benzene, pentafluoro-, lithium complex;Pentafluorophenyllithium; Perfluorophenyllithium

Chemical Property of Lithium,(2,3,4,5,6-pentafluorophenyl)-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3:
• Safety Statements: Explodes on contact with water or deuterium oxide. W"> 2O and F−. See also FLUORIDES and LITHIUM COMPOUNDS." target="_blank">Explodes on contact with water or deuterium oxide. W

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Lithium,(2,3,4,5,6-pentafluorophenyl)-

There total 17 articles about Lithium,(2,3,4,5,6-pentafluorophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.1%

→ pentafluorophenyl lithium (1076-44-4)

Guidance literature:

Reference yield: 94.3%

bromopentafluorobenzene (344-04-7) → pentafluorophenyl lithium (1076-44-4)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; at -78 - 20 ℃; for 2h; Inert atmosphere;

Reference yield: 85.0%

bromopentafluorobenzene (344-04-7) + N,N-dimethylaniline hydrochloride (5882-44-0) → N,N-dimethylanilinium tetrakis (pentafluorophenyl) borate + pentafluorophenyl lithium (1076-44-4)

Guidance literature:

With n-butyllithium; In ethyl octyl ether;

upstream raw materials:

bromopentafluorobenzene

Pentafluorobenzene

potassium tert-butylate

2,3,4,5,6-pentafluorotoluene

Downstream raw materials:

trans-β-Jod-perfluorstyrol

tetrakis(pentafluorophenyl)sulfur

Decafluorobenzil

bis(perfluorophenyl) selenide

Refernces

• 1、 Bl?sing, Kevin,Bresien, Jonas,Maurer, Steffen,Schulz, Axel,Villinger, Alexander. "Trimethylsilyl Pseudohalide Adducts of GaCl3 and B(C6F5)3". supporting information. p. 1913 - 1920. Retrieved 2021/05/10.
• 2、 Delany, Eoghan G.,Kaur, Satnam,Cummings, Steven,Basse, Kristoffer,Wilson, David J. D.,Dutton, Jason L.. "Revisiting the Perfluorinated Trityl Cation". supporting information. p. 5298 - 5302. Retrieved 2019/03/11.