n-Propyllithium

Base Information

• Chemical Name: n-Propyllithium
• CAS No.: 2417-93-8
• Molecular Formula: C3H7 Li
• Molecular Weight: 50.0296
• Hs Code.: 2901100000
• European Community (EC) Number: 658-066-7
• Mol file: 2417-93-8.mol

Synonyms:n-propyllithium;2417-93-8;propyl lithium;n-propyl lithium;Lithium, propyl-;OGDGPURISKPUBG-UHFFFAOYSA-N;AKOS006284564

Chemical Property of n-Propyllithium

Chemical Property:

• PSA: 0.00000
• LogP: 1.36400
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 50.07077866
• Heavy Atom Count: 4
• Complexity: 3.2

Purity/Quality:

99% ^*data from raw suppliers

N-PROPYLLITHIUM 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3:
• Safety Statements: Ignites spontaneously in air. See also LITHIUM COMPOUNDS.:;"> LITHIUM COMPOUNDS." target="_blank">Ignites spontaneously in air. See also LITHIUM COMPOUNDS.:

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Li+].CC[CH2-]

Technology Process of n-Propyllithium

There total 11 articles about n-Propyllithium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

propyl bromide (106-94-5) → propyllithium (2417-93-8)

Guidance literature:

With lithium; In diethyl ether; ultrasonic agitation;

DOI:10.1021/ja00547a016

Reference yield:

1-Chloropropane (540-54-5) → propyllithium (2417-93-8)

Guidance literature:

With diethyl ether; lithium;

Reference yield:

1-iodo-propane (107-08-4) → propyllithium (2417-93-8)

Guidance literature:

With tert.-butyl lithium; In diethyl ether; -78 deg C, 0.5 h; RT, 1 h;

upstream raw materials:

1-Chloropropane

di-n-propylmercury

propyl bromide

1-iodo-propane

Downstream raw materials:

tripropylsilane

butyraldehyde

2-(n-propyl)cyclohexanone

1-n-propyl-1-cyclohexanol

Refernces

• 1、 Crestani, Marco G.,Hickey, Anne K.,Gao, Xinfeng,Pinter, Balazs,Cavaliere, Vincent N.,Ito, Jun-Ichi,Chen, Chun-Hsing,Mindiola, Daniel J.. "Room temperature dehydrogenation of ethane, propane, linear alkanes C4-C8, and some cyclic alkanes by titanium-carbon multiple bonds". supporting information. p. 14754 - 14767. Retrieved 2013/10/22.
• 2、 Enders, Dieter,Chelain, Evelyne,Raabe, Gerhard. "Enantioselective synthesis of 1,2-diamines via nucleophilic 1,2-addition to dibenzylamino-acetaldehyde-SAMP-hydrazone". . p. 299 - 306. Retrieved 2007/10/03.