trinitromethanide

Base Information

• Chemical Name: trinitromethanide
• CAS No.: 20143-63-9
• Molecular Formula: CN₃O₆
• Molecular Weight: 150.027
• Mol file: 20143-63-9.mol

Synonyms:trinitromethanide

Chemical Property of trinitromethanide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trinitromethanide

There total 6 articles about trinitromethanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

fluorotrinitromethane (1840-42-2) + phenylmagnesium chloride (100-59-4) → trinitromethanide (20143-63-9) + fluorodinitromethane anion (26448-08-8) + 1,4-cyclopentadien-1-ylbenzene (1961-93-9) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

In tetrahydrofuran; at -50°C; further products;

Reference yield:

tetranitromethane (509-14-8) + C8H7O3 (103776-50-7) → trinitromethanide (20143-63-9) + 4-Carboxybenzaldehyde (619-66-9)

Guidance literature:

In phosphate buffer; at 20 ℃; pH=6.6; Kinetics;

DOI:10.1021/ja993570b

Reference yield:

tetrahydro-2-methyl-2-furyl hydroperoxide (23277-12-5) + tetranitromethane (509-14-8) → 5-Hydroxy-2-pentanone (1071-73-4) + 3-Chloropropyl acetate (628-09-1) + trinitromethanide (20143-63-9)

Guidance literature:

With sodium perchlorate; iron(III) perchlorate; sodium chloride; In water; at 25 ℃; Rate constant; also without additives; also with other additives (1,10-Phen, NaBr, Na₂SO₄, NaH₂PO₄);

DOI:10.1007/BF00954361

upstream raw materials:

tetrahydro-2-methyl-2-furyl hydroperoxide

tetranitromethane

2-methyl-1,1-(4,4-dimethoxydiphenyl)-1-propene

hexamethylbenzene-tetranitromethane complex

Downstream raw materials:

m-nitrophenyltrinitromethane

1-nitro-4-trinitromethylbenzene

1-Nitro-2-trinitromethyl-benzene

Trinitro-(4-chlorphenyl)-methan

Refernces

• 1、 Konya, Klara G.,Paul, Thomas,Lin, Shuqiong,Lusztyk, Janusz,Ingold. "Laser flash photolysis studies on the first superoxide thermal source. First direct measurements of the rates of solvent-assisted 1,2-hydrogen atom shifts and a proposed new mechanism for this unusual rearrangement". . p. 7518 - 7527. Retrieved 2007/10/03.
• 2、 P'yankova, V. I.,Altukhov, K. V.,Perekalin, V. V.,Berkova, G. A.,Pozdnyakov, V. P.. "NITROCARBOCATIONS IN REACTION OF TETRANITROMETHANE WITH ALKENES". . p. 341 - 344. Retrieved 2007/10/02.