Chromium,tris(2,2'-bipyridine-kN1,kN1')-, (OC-6-11)-

Base Information

• Chemical Name: Chromium,tris(2,2'-bipyridine-kN1,kN1')-, (OC-6-11)-
• CAS No.: 14751-89-4
• Molecular Formula: C30H24 Cr N6
• Molecular Weight: 520.557
• Mol file: 14751-89-4.mol

Synonyms:Chromium,tris(2,2'-bipyridine)- (6CI,7CI,8CI); Chromium, tris(2,2'-bipyridine-N,N')-,(OC-6-11)-; Tris(2,2'-bipyridine)chromium; Tris(2,2'-bipyridine)chromium(0)

Chemical Property of Chromium,tris(2,2'-bipyridine-kN1,kN1')-, (OC-6-11)-

Chemical Property:

• PSA: 23.28000
• LogP: 1.66020

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Chromium,tris(2,2'-bipyridine-kN1,kN1')-, (OC-6-11)-

There total 1 articles about Chromium,tris(2,2'-bipyridine-kN1,kN1')-, (OC-6-11)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

[2,2]bipyridinyl (366-18-7) + chromium(III) chloride (10025-73-7,16284-59-6) → tris(2,2'-bipyridine)chromium (14751-89-4)

Guidance literature:

With sodium amalgam; In tetrahydrofuran; under oxygen-free nitrogen or argon or vac.; 2,2'-bpyridin was added toa suspn. of CrCl3 and sodium amalgam in THF; after stirring for 24 h atroom temp. and filtering, the soln. was reduced under vac.; diethylether was slowly added; ppt. was collected, washed with petroleum (b.p.40-60°C) and recrystd. from THF-diethylether;

DOI:10.1016/S0277-5387(00)80989-4

upstream raw materials:

[2,2]bipyridinyl

chromium(III) chloride