2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indecene

Base Information

• Chemical Name: 2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indecene
• CAS No.: 189264-27-5
• Molecular Formula: C₂₃H₂₇BF₂N₂
• Molecular Weight: 380.289
• Mol file: 189264-27-5.mol

Synonyms:2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indecene

Chemical Property of 2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indecene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indecene

There total 2 articles about 2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(Z)-3-ethyl-5-((4-ethyl-3,5-dimethyl-2H-pyrrol-2-ylidene)-(phenyl)methyl)-2,4-dimethyl-1H-pyrrole (917201-08-2) → 2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indecene (189264-27-5)

Guidance literature:

(Z)-3-ethyl-5-((4-ethyl-3,5-dimethyl-2H-pyrrol-2-ylidene)-(phenyl)methyl)-2,4-dimethyl-1H-pyrrole; With triethylamine; In dichloromethane; for 1h;

With boron trifluoride diethyl etherate; In dichloromethane; at 25 ℃; Further stages.;

DOI:10.1021/jo702346s

Reference yield:

2,4-dimethyl-3-ethyl-pyrrole (517-22-6) + benzoyl chloride (98-88-4) → 2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indecene (189264-27-5)

Guidance literature:

2,4-dimethyl-3-ethyl-pyrrole; benzoyl chloride; In dichloromethane;

With BF*OEt₂; triethylamine; Further stages.;

DOI:10.1016/j.tetlet.2007.06.021

Reference yield: 30.0%

2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indecene (189264-27-5) + 4-((2-(bis(pyridin-2-ylmethyl)amino)ethyl)(methyl)amino)benzaldehyde → C45H49BF2N6

Guidance literature:

With piperidine; acetic acid; In toluene; at 120 ℃; for 24h;

DOI:10.1016/j.tetlet.2007.06.021

upstream raw materials:

2,4-dimethyl-3-ethyl-pyrrole

benzoyl chloride

(Z)-3-ethyl-5-((4-ethyl-3,5-dimethyl-2H-pyrrol-2-ylidene)-(phenyl)methyl)-2,4-dimethyl-1H-pyrrole

Refernces

• 1、 Coskun, Ali,Deniz, Erhan,Akkaya, Engin U.. "A sensitive fluorescent chemosensor for anions based on a styryl-boradiazaindacene framework". . p. 5359 - 5361. Retrieved 2007.