DI-Tert-butyl-methyl-silane

Base Information

• Chemical Name: DI-Tert-butyl-methyl-silane
• CAS No.: 56310-20-4
• Molecular Formula: C9H22Si
• Molecular Weight: 158.359
• Nikkaji Number: J267.366E
• Mol file: 56310-20-4.mol

Synonyms:DI-TERT-BUTYL-METHYL-SILANE;10beta-Hydroperoxy Norethindrone Acetate;ditert-butyl(methyl)silane;13236-11-8;F14038

Chemical Property of DI-Tert-butyl-methyl-silane

Chemical Property:

• Vapor Pressure: 5.41mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: 1.4293
• Boiling Point: 35.6 °C
• Flash Point: 35.6 °C
• PSA: 0.00000
• Density: 0,758 g/cm3
• LogP: 3.44350
• Storage Temp.: Refrigerator
• Solubility.: Chloroform, Methanol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 158.149077236
• Heavy Atom Count: 10
• Complexity: 88.9

Purity/Quality:

98% ^*data from raw suppliers

Di-tert-Butylmethylsilane ^*data from reagent suppliers

Safty Information:

• Statements: 10-36/37/38
• Safety Statements: 16-26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)[SiH](C)C(C)(C)C
• Uses: Di-tert-butylmethylsilane is useful in the synthesis of bis(phosphine)(hydrido)(silyl)platinum(II) complex.

Technology Process of DI-Tert-butyl-methyl-silane

There total 3 articles about DI-Tert-butyl-methyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

Dichloromethylsilane (75-54-7) + tert.-butyl lithium (594-19-4) → 1,1'-di-tert-butyl-1-methyl silane (56310-20-4)

Guidance literature:

Dichloromethylsilane; tert.-butyl lithium; In pentane; at 0 ℃; Inert atmosphere; Schlenk technique;

at 20 ℃; for 48h;

DOI:10.1021/jacs.1c03236

Reference yield:

Di-tert-butyldichlorosilane (18395-90-9) + methyllithium (917-54-4) → 1,1'-di-tert-butyl-1-methyl silane (56310-20-4)

Guidance literature:

DOI:10.1021/ja00846a037

Reference yield:

di-tert-butylchlorosilane (56310-18-0) + methyllithium (917-54-4) → 1,1'-di-tert-butyl-1-methyl silane (56310-20-4)

Guidance literature:

for 72h;

DOI:10.1021/ja00846a037

upstream raw materials:

Dichloromethylsilane

tert.-butyl lithium

Di-tert-butyldichlorosilane

methyllithium

Downstream raw materials:

Di-tert-butylmethylsilanol

Di-tert-butylmethylsilyl Trifluoromethanesulfonate

Brom-di-tert-butylmethylsilan

di-tert-butylmethylsilylsodium

Refernces