1-ETHYLADAMANTANE

Base Information

• Chemical Name: 1-ETHYLADAMANTANE
• CAS No.: 770-69-4
• Molecular Formula: C12H20
• Molecular Weight: 164.291
• Hs Code.: 2902199090
• Mol file: 770-69-4.mol

Synonyms:1-Ethyladamantane;

Chemical Property of 1-ETHYLADAMANTANE

Chemical Property:

• Vapor Pressure: 0.232mmHg at 25°C
• Melting Point: -57.7℃
• Refractive Index: 1.4950 (589.3 nm 20℃)
• Boiling Point: 214.1 °C at 760 mmHg
• Flash Point: 69.7 °C
• PSA: 0.00000
• Density: 0.956 g/cm³
• LogP: 3.61280
• Storage Temp.: 2-8°C
• Solubility.: Chloroform (Sparingly), Methanol (Slightly), Ethyl Acetate (Slightly)

Purity/Quality:

99% ^*data from raw suppliers

1-Ethyladamantane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 1-Ethyladamantane is a conversion product of perhydroacenaphthene.

Technology Process of 1-ETHYLADAMANTANE

There total 39 articles about 1-ETHYLADAMANTANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2-(adamant-1-yl)ethanol (6240-11-5) → 1-ethyladamantane (770-69-4)

Guidance literature:

With 4-methyl-benzoic acid methyl ester; tetrabutylammonium tetrafluoroborate; In N,N-dimethyl-formamide; at 60 ℃; for 6h; Electrolysis; Inert atmosphere;

DOI:10.1055/s-0031-1290778

Reference yield: 95.0%

ethyl bromide (74-96-4) + adamantane (281-23-2) → 1-ethyladamantane (770-69-4)

Guidance literature:

With Rh(PPh₃)3Cl; In dichloromethane; at 150 ℃; for 3h;

DOI:10.1134/S0965544106030030

Reference yield: 90.8%

triethyl borane (97-94-9) + 1-adamanthanol (768-95-6) → adamantane (281-23-2) + 1-ethyladamantane (770-69-4)

Guidance literature:

With trifluorormethanesulfonic acid; In 1,1,2-Trichloro-1,2,2-trifluoroethane; 1.) -30 deg C 2.) room temp.;

DOI:10.1021/jo00008a035

upstream raw materials:

1-Adamantyl bromide

ethylmagnesium bromide

ethene

adamantane

Downstream raw materials:

adamantane

1-methyl-adamantane

3-ethyladamantane-1-ol

acetate de ethyl-3 adamantyl-1

Refernces

• 1、 Berger, Kathleen J.,Driscoll, Julia L.,Yuan, Mingbin,Dherange, Balu D.,Gutierrez, Osvaldo,Levin, Mark D.. "Direct Deamination of Primary Amines via Isodiazene Intermediates". supporting information. p. 17366 - 17373. Retrieved 2021/11/04.
• 2、 Maazaoui, Radhouan,Pin-Nó, María,Gervais, Kevin,Abderrahim, Raoudha,Ferreira, Franck,Perez-Luna, Alejandro,Chemla, Fabrice,Jackowski, Olivier. "Domino Methylenation/Hydrogenation of Aldehydes and Ketones by Combining Matsubara's Reagent and Wilkinson's Catalyst". supporting information. p. 5732 - 5737. Retrieved 2016/12/14.